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多孔介质期刊
影响因子: 1.49 5年影响因子: 1.159 SJR: 0.43 SNIP: 0.671 CiteScore™: 1.58

ISSN 打印: 1091-028X
ISSN 在线: 1934-0508

多孔介质期刊

DOI: 10.1615/JPorMedia.v14.i4.70
pages 353-361

EFFECT OF POROUS ADDITIVES ON PROPERTIES OF THE ATTAPULGITE-BASED CaCl2 COMPOSITES FOR COOLING APPLICATIONS

X. L. Yao
College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009, China
Y. Tang
College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009, China
Hai-Jun Chen
College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009, China
Q. Cui
College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009, China
L. L. Sheng
College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009, China
K. Zheng
College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009, China
X. J. Chen
College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009, China
H. Q. Yao
College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009, China

ABSTRACT

The effects on the properties of composites when adding porous materials (13X zeolite, silica gel, or alumina) were investigated based on the preparation and performance testing of attapulgite-based CaCl2 composites. The adsorption performance of the composites was carried out using the static weighing method, and the desorption behavior was done through thermal analysis. Also, the composite adsorbents were characterized by x-ray diffraction. The results show that low 13X zeolite and alumina additives could yield a positive water adsorption effect and improve the dispersion of CaCl2 in composite adsorbents, thus increasing their water adsorption properties at low relative humidity. The desorption temperature of the composite adsorbents was not affected by the addition of lower than 25% of porous materials. The adsorption stability of the composites was improved for suppression of CaCl2 agglomeration due to the dispersion promoting effect of porous materials. At a relative humidity of 20%, water uptakes on the composite with 20% 13X zeolite content could reach 0.36kg/kg, which is 20% higher than the original attapulgite-based CaCl2 composite.