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高温材料处理:国际期刊
ESCI SJR: 0.176 SNIP: 0.48 CiteScore™: 1.3

ISSN 打印: 1093-3611
ISSN 在线: 1940-4360

高温材料处理:国际期刊

DOI: 10.1615/HighTempMatProc.v4.i3.70
20 pages

STANDARD THERMODYNAMIC FUNCTIONS OF DIATOMIC PRODUCTS OF THERMAL DECOMPOSITION OF SF6

O. Zivny
Department of Theoretical and Physical Chemistry, Faculty of Science, Masaryk University, Kotlarska 2, 611 37 Brno, Czech Republic

ABSTRACT

Standard thermodynamic functions of nine possible both neutral and single charged products of thermal decomposition of SF6 were computed by the method of direct summation and tabulated in form of approximation coefficients up to 20 000 K. Obtained results were discussed and compared With the existing literature data. Furthermore, influence of excited electronic states was briefly studied. Finally, the equilibrium composition was performed in the case of the decomposition of pure SF6 using the calculated data.


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