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无线电物理和天文学期刊

每年出版 4 

ISSN 打印: 2152-274X

ISSN 在线: 2152-2758

MICROWAVE SPECTROSCOPY OF TORSION VIBRATIONS IN MOLECULES: APPROXIMATION OF STRICT COUPLING BETWEEN THE STRUCTURAL TORSIONAL PARAMETERS ρ AND F IN THE RHO AXIS METHOD

卷 3, 册 2, 2012, pp. 159-167
DOI: 10.1615/RadioPhysicsRadioAstronomy.v3.i2.80
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摘要

In the paper, the approximation of strict coupling between the structural torsional parameters F and ρ in the Rho axis method and its applicability to analyzing the observed molecular spectra are considered for the molecules with methyl top hindered internal rotation. The functional relation between the F and ρ parameters which is implied in the rigid molecular structure approximation makes it possible to replace variation of these two parameters by variation of a single structural parameter, namely, of the moment of inertia of the C group which is in torsion motion. The approximation in question has been verified through processing spectrum measurement data for a number of molecules which spectra have been analyzed in the literature using standard Rho axis method. It is shown that structural distortions in molecules with hindered internal rotation of the C group, which are associated in the standard model of the Rho axis method with separate variation of the F and ρ parameters, are insignificant for the ground torsional state and can be accounted for through considering the fourth-order terms of the Hamiltonian in the course of fitting the spectra of excited torsional states.

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