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Catalysis in Green Chemistry and Engineering

ISSN 打印: 2572-9896
ISSN 在线: 2572-990X

Catalysis in Green Chemistry and Engineering

DOI: 10.1615/CatalGreenChemEng.2019029780
pages 1-10

HYDROPROCESSING OF AQUEOUS PHASE OF PYROLYSIS OIL OVER NiMo/Al2O3–SiO2 IN MICROCHANNEL REACTOR

Mukesh K. Poddar
CSIR-Indian Institute of Petroleum, Dehradun, India; Indian Institute of Technology, Roorkee, India
Satyendra Kumar
CSIR-Indian Institute of Petroleum, Dehradun, India
Pankaj Kumar Das
Indian Institute of Petroleum, Council of Scientific and Industrial Research, Dehradun-248005, India
Mannar R. Maurya
Indian Institute of Technology, Roorkee, India
Anil K. Sinha
Indian Institute of Petroleum, Council of Scientific and Industrial Research, Dehradun-248005, India; Academy of Scientific and Innovative Research, CSIR-IIP, Dehradun 248005, India

ABSTRACT

Sulfided NiMo catalyst supported on mesoporous silica-alumina and coated in a microchannel reactor was studied for the hydroprocessing of aqueous-phase of bio-oil (BO) obtained from pyrolysis of de-oiled jatropha curcas seeds cake (JCC). The oxygen content of the dissolved organic compound in the aqueous phase was reduced to a trace amount after hydroprocessing. A clear organic hydrocarbon phase product obtained after hydroprocessing contained 5%–45% gasoline (< C9), 5%–60% kerosene (C9–C14), 15%–40% diesel (> C14), with 15%–65% alkanes, 0%–5% polyaromatic hydrocarbons (PAH), negligible cycloalkanes and aromatics, with 30%–75% unreacted and residues. Maximum hydrocarbon yield (~ 65%) was obtained at 648 K, 0.25 LHSV, and 70 bar, with 35% residues and PAH. The water obtained after hydroprocessing contained few organics (< 5%).

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