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Catalysis in Green Chemistry and Engineering

ISSN 打印: 2572-9896
ISSN 在线: 2572-990X

Catalysis in Green Chemistry and Engineering

DOI: 10.1615/CatalGreenChemEng.2020032832
pages 1-12

CLAISEN REARRANGEMENT OF ALLYL-2,6-DIMETHYLPHENYL ETHER OVER A SOLID SUPERACID UDCaT-5 CATALYST

Sharad V. Lande
Department of Chemical Engineering, Institute of Chemical Technology, Nathalal Parekh, Marg, Matunga,Mumbai 400019, India
Ganapati D. Yadav
Department of Chemical Engineering, Institute of Chemical Technology, University of Mumbai, Nathalal Parekh Marg, Matunga, Mumbai 400019, India

ABSTRACT

4-Allyl-2,6-xylenol finds several applications in a variety of industries. It is prepared by Claisen rearrangement of allyl-2,6-dimethylphenyl ether to 4-allyl-2,6-xylenol using various heterogeneous acid catalysts. Catalysts such as heteropolyacid supported on mesoporous silica, cesium modified heteropolyacid supported on clay, and zirconia based mesoporous UDCaT-5 were used for the studies. UDCaT-5 was found to be superior, reusable, and 100% selective toward the desired product. A kinetic model including mechanistic interpretation is provided.

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