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Catalysis in Green Chemistry and Engineering

每年出版 4 

ISSN 打印: 2572-9896

ISSN 在线: 2572-990X

H-Index: 2

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CLAISEN REARRANGEMENT OF ALLYL-2,6-DIMETHYLPHENYL ETHER OVER A SOLID SUPERACID UDCaT-5 CATALYST

卷 3, 册 1, 2020, pp. 1-12
DOI: 10.1615/CatalGreenChemEng.2020032832
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摘要

4-Allyl-2,6-xylenol finds several applications in a variety of industries. It is prepared by Claisen rearrangement of allyl-2,6-dimethylphenyl ether to 4-allyl-2,6-xylenol using various heterogeneous acid catalysts. Catalysts such as heteropolyacid supported on mesoporous silica, cesium modified heteropolyacid supported on clay, and zirconia based mesoporous UDCaT-5 were used for the studies. UDCaT-5 was found to be superior, reusable, and 100% selective toward the desired product. A kinetic model including mechanistic interpretation is provided.

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