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Telecommunications and Radio Engineering
SJR: 0.202 SNIP: 0.2 CiteScore™: 0.23

ISSN Druckformat: 0040-2508
ISSN Online: 1943-6009

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Telecommunications and Radio Engineering

DOI: 10.1615/TelecomRadEng.v74.i5.60
pages 431-443

SYNTHESIS OF KESTERITE LAYERS OBTAINED BY SULFURIZATION OF ELECTRODEPOSITED METAL PRECURSORS

A.V. Momotenko
National Technical University "Kharkiv Polytechnic Institute" 21,Frunze Str., Kharkiv, 61002, Ukraine
N. P. Klochko
National Technical University “Kharkiv Polytechnical Institute” 21 Frunze St., 61002 Kharkiv, Ukraine
V.M. Lyubov
National Technical University "Kharkiv Polytechnic Institute" 21,Frunze Str., Kharkiv, 61002, Ukraine
V. R. Kopach
National Technological University "Kharkiv Polytechnic Institute", 21, Frunze St., 61002 Kharkiv
G.S. Khrypunov
National Technical University "Kharkiv Polytechnic Institute" 21,Frunze Str., Kharkiv, 61002, Ukraine

ABSTRAKT

Surface morphology of electrochemically deposited film stacks of copper, tin and zinc as metal precursors of kesterite layers was studied. The optimal sequence of metallic films for precursors, the atomic ratio of the components of electrodeposited precursors, electrodeposition and sulfurization modes that provide acceptable structural parameters of the crystalline kesterite phase were determined. Phase composition and optical properties of kesterite layers were presented resulted in technique development of single-phase microcrystalline kesterite synthesis for utilization as effective, cheap and affordable absorbers of solar cells of a new generation.


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