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International Journal of Energy for a Clean Environment

Publicado 8 números por año

ISSN Imprimir: 2150-3621

ISSN En Línea: 2150-363X

SJR: 0.597 SNIP: 1.456 CiteScore™:: 3.7 H-Index: 18

Indexed in

DEVELOPMENT OF REDUCED CHEMICAL MECHANISMS FOR NITROGEN CONTAINING FUELS

Volumen 5, Edición 3, 2004, 14 pages
DOI: 10.1615/InterJEnerCleanEnv.v5.i3.70
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SINOPSIS

A method for automatic reduction of reaction mechanisms has been developed and applied to a homogeneous model of a staged combustor simulation using a sequence of a PSR (Perfectly Stirred Reactor) and a PFR (Plug Flow Reactor) fuelled with ethylene (C2H4) doped with monomethylamine (CH3NH2) as a model compound for fuel bound nitrogen. A measure of species' lifetimes combined with the species' sensitivity is called the Level of Importance (LOI) and species with a LOI lower than a specified limit are selected as steady states. The original mechanism is reduced to a minimum of 22 species. It is found that the error in NO mole fractions relative to the detailed case amounts to single percentage units up to a lifetime limit of 10 μs (38 remaining species), and for the maximum achievable degree of reduction (22 remaining species), 3.9% in the PSR and 4.0% after the PFR.

CITADO POR
  1. Houshfar Ehsan, Skreiberg Øyvind, Glarborg Peter, Løvås Terese, Reduced chemical kinetic mechanisms for NOx emission prediction in biomass combustion, International Journal of Chemical Kinetics, 44, 4, 2012. Crossref

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