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Catalysis in Green Chemistry and Engineering

Publicado 4 números por año

ISSN Imprimir: 2572-9896

ISSN En Línea: 2572-990X

H-Index: 2

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HYDROPROCESSING OF AQUEOUS PHASE OF PYROLYSIS OIL OVER NiMo/Al2O3–SiO2 IN MICROCHANNEL REACTOR

Volumen 2, Edición 1, 2019, pp. 1-10
DOI: 10.1615/CatalGreenChemEng.2019029780
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SINOPSIS

Sulfided NiMo catalyst supported on mesoporous silica-alumina and coated in a microchannel reactor was studied for the hydroprocessing of aqueous-phase of bio-oil (BO) obtained from pyrolysis of de-oiled jatropha curcas seeds cake (JCC). The oxygen content of the dissolved organic compound in the aqueous phase was reduced to a trace amount after hydroprocessing. A clear organic hydrocarbon phase product obtained after hydroprocessing contained 5%–45% gasoline (< C9), 5%–60% kerosene (C9–C14), 15%–40% diesel (> C14), with 15%–65% alkanes, 0%–5% polyaromatic hydrocarbons (PAH), negligible cycloalkanes and aromatics, with 30%–75% unreacted and residues. Maximum hydrocarbon yield (~ 65%) was obtained at 648 K, 0.25 LHSV, and 70 bar, with 35% residues and PAH. The water obtained after hydroprocessing contained few organics (< 5%).

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