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High Temperature Material Processes: An International Quarterly of High-Technology Plasma Processes

Published 4 issues per year

ISSN Print: 1093-3611

ISSN Online: 1940-4360

The Impact Factor measures the average number of citations received in a particular year by papers published in the journal during the two preceding years. 2017 Journal Citation Reports (Clarivate Analytics, 2018) IF: 0.4 The Immediacy Index is the average number of times an article is cited in the year it is published. The journal Immediacy Index indicates how quickly articles in a journal are cited. Immediacy Index: 0.1 The Eigenfactor score, developed by Jevin West and Carl Bergstrom at the University of Washington, is a rating of the total importance of a scientific journal. Journals are rated according to the number of incoming citations, with citations from highly ranked journals weighted to make a larger contribution to the eigenfactor than those from poorly ranked journals. Eigenfactor: 0.00005 The Journal Citation Indicator (JCI) is a single measurement of the field-normalized citation impact of journals in the Web of Science Core Collection across disciplines. The key words here are that the metric is normalized and cross-disciplinary. JCI: 0.07 SJR: 0.198 SNIP: 0.48 CiteScore™:: 1.1 H-Index: 20

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MIXING ENTHALPY OF TbCl3- MCI LIQUID MIXTURES (M = Li, Na, K, Rb, Cs)

Volume 2, Issue 4, 1998, pp. 483-496
DOI: 10.1615/HighTempMatProc.v2.i4.40
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ABSTRACT

The molar enthalpies of mixing, ΔmixHm in the binary liquid systems TbCI3 - MCI ( M = Li, Na, K, Rb, Cs ) have been measured with a Calvet - type high temperature microcalorimeter over the entire composition range with an accuracy of about 6%. Mixing of the two liquid components was achieved by using the "break-off ampoule technique". All the investigated systems show negative enthalpies of mixing with a minimum value of approximately -2.4, -9.9, -20.5, -26.0 and -28.8 kJ mol−1, for M = Li, Na, K, Rb and Cs, respectively occuring at nearly the same molar fraction of TbCl3, xTbCl3 ≈ respectively, at XTbCl3 ∼0.4. The molar enthalpies of formation ΔformHm (3MCl,TbCl3,1) for M = Li, Na, K at 1109 K and for M = Rb and Cs at 1175 K, arising from the reaction 3MC1 (1) +TbC13 (1) = (3MCl,TbCl3) (1) are found to be -9.6, -36.1, -72.6, -87.4 and-97.6 kJ mol−1, respectively. The least-squares coefficients A,B, C, D in the equation λ (kJmol−1)= A + Bx + Cx2 + Dx3 where λ is an interaction parameter are also reported.

CITED BY
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  10. Yin Huiqin, Lin Jian, Hu Biao, Liu Wenguan, Guo Xiaofeng, Liu Qi, Tang Zhongfeng, Thermodynamic description of the constitutive binaries of the NaCl-KCl-UCl3-PuCl3 system, Calphad, 70, 2020. Crossref

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  12. Schorne-Pinto Juliano, Yingling Jacob A., Christian Matthew S., Mofrad Amir M., Aslani Mahmoud A. A., Besmann Theodore M., Correlational Approach to Predict the Enthalpy of Mixing for Chloride Melt Systems, ACS Omega, 7, 1, 2022. Crossref

  13. Yin Huiqin, Wu Xiaomin, Ling Changjian, Lai Xing, Hu Biao, Tang Zhongfeng, Thermodynamic optimization of the constitutive binaries of the LiCl/RbCl/CaCl2-NaCl-UCl3-PuCl3 systems, Calphad, 77, 2022. Crossref

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