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International Journal of Energetic Materials and Chemical Propulsion

年間 6 号発行

ISSN 印刷: 2150-766X

ISSN オンライン: 2150-7678

The Impact Factor measures the average number of citations received in a particular year by papers published in the journal during the two preceding years. 2017 Journal Citation Reports (Clarivate Analytics, 2018) IF: 0.7 To calculate the five year Impact Factor, citations are counted in 2017 to the previous five years and divided by the source items published in the previous five years. 2017 Journal Citation Reports (Clarivate Analytics, 2018) 5-Year IF: 0.7 The Immediacy Index is the average number of times an article is cited in the year it is published. The journal Immediacy Index indicates how quickly articles in a journal are cited. Immediacy Index: 0.1 The Eigenfactor score, developed by Jevin West and Carl Bergstrom at the University of Washington, is a rating of the total importance of a scientific journal. Journals are rated according to the number of incoming citations, with citations from highly ranked journals weighted to make a larger contribution to the eigenfactor than those from poorly ranked journals. Eigenfactor: 0.00016 The Journal Citation Indicator (JCI) is a single measurement of the field-normalized citation impact of journals in the Web of Science Core Collection across disciplines. The key words here are that the metric is normalized and cross-disciplinary. JCI: 0.18 SJR: 0.313 SNIP: 0.6 CiteScore™:: 1.6 H-Index: 16

Indexed in

DEVELOPMENT OF A NEW GENERATION OF INSENSITIVE EXPLOSIVES AND GUN PROPELLANTS

巻 9, 発行 2, 2010, pp. 107-132
DOI: 10.1615/IntJEnergeticMaterialsChemProp.v9.i2.10
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要約

For the last few decades, DRDC Valcartier has been involved in the synthesis of energetic thermoplastic elastomers (ETPEs) based on linear glycidyl azide polymer (GAP). A new generation of energetic polyester homopolymers was also developed at DRDC Valcartier, and their polymerizations yielded energetic thermoplastic elastomers containing ester groups that could be degraded. Some ETPEs were also synthesized based on polynitratomethylmethyl-oxetane (PolyNIMMO) and polyglycidyl nitrate (Polyglyn). These energetic homopolymers were used as macromonomers and were reacted with 4,4'− methylenebis (phenylisocyanate) to yield copolyurethane thermoplastic elastomers. These ETPEs are physically cross-linked rubbery materials that can be dissolved, recycled, and then be utilized to provide the basis for a new generation of insensitive explosives and high-energy low-vulnerability ammunition (HELOVA) gun propellants. The mechanical properties of these ETPEs were adjusted so that these compounds could be used as binders in propellant and explosive formulations demonstrating an insensitive character. First, the ETPEs were introduced into gun propellant formulations to yield HELOVA gun propellants. The latest developments yielded green HELOVA gun propellants with improved energy. Moreover, an insensitive explosive named XRT for "experimental rubbery TNT" was developed and led directly to the development of a new insensitive recyclable green explosive. Furthermore, our understanding of the environmental impacts of explosives during live-fire training led us to the development of concepts for a green weapon that will contain both green explosives and gun propellants. A major project named RIGHTTRAC for "revolutionary insensitive green and healthier training technology with reduced adverse contamination" was initiated in 2008 and will produce a green weapon based on these concepts. Because ETPEs are recyclable, they will allow for easier disposal and reuse of the new formulations at the end of their life cycle. This paper describes the syntheses of these ETPEs, the strategies that yielded the HELOVA gun propellants, the XRT and green explosives, the results describing their properties and insensitive characters, and the RIGHTTRAC project, which includes the concept and incorporation of green explosives and gun propellants.

によって引用された
  1. You Jong Sung, Kang Shin Chun, Kweon Soon Kil, Kim Ho Lim, Ahn Yong Hwan, Noh Si Tae, Thermal decomposition kinetics of GAP ETPE/RDX-based solid propellant, Thermochimica Acta, 537, 2012. Crossref

  2. Walsh Michael R., Walsh Marianne E., Taylor Susan, Ramsey Charles A., Ringelberg David B., Zufelt Jan E., Thiboutot Sonia, Ampleman Guy, Diaz Emmanuela, Characterization of PAX-21 Insensitive Munition Detonation Residues, Propellants, Explosives, Pyrotechnics, 38, 3, 2013. Crossref

  3. Kuperman Roman G., Simini Mike, Checkai Ronald T., Dodard Sabine G., Sarrazin Manon, Hawari Jalal, Paquet Louise, Sunahara Geoffrey I., Di Toro Dominic M., Allen Herbert E., Kuo Dave Ta Fu, Torralba-Sanchez Tifany L., Developing earthworm bioconcentration factors of nitrogen-based compounds for predicting environmentally significant parameters for new munition compounds in soil, Applied Soil Ecology, 104, 2016. Crossref

  4. Gurtowski Luke A., Griggs Chris S., Gude Veera G., Shukla Manoj K., An integrated theoretical and experimental investigation of insensitive munition compounds adsorption on cellulose, cellulose triacetate, chitin and chitosan surfaces, Journal of Environmental Sciences, 64, 2018. Crossref

  5. Shen Jinpeng, Liu Zhitao, Xu Bin, Chen Feiyun, Zhu Yao, Fu You, Kline Dylan J., Liao Xin, Wang Zeshan, Tuning the thermal, mechanical, and combustion properties of NC-TEGDN-RDX propellants via incorporation of graphene nanoplates, Journal of Energetic Materials, 38, 3, 2020. Crossref

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