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Computational Thermal Sciences: An International Journal
ESCI SJR: 0.249 SNIP: 0.434 CiteScore™: 0.7

ISSN 印刷: 1940-2503
ISSN オンライン: 1940-2554

Computational Thermal Sciences: An International Journal

DOI: 10.1615/ComputThermalScien.2013006342
pages 189-194

THE STATISTICAL THEORY OF MONOMOLECULAR FULLERENE FILM FORMATION ON THE CRYSTAL SURFACE

Svetlana Yu. Zaginaichenko
Institute for Problems of Materials Science of NAS of Ukraine, Krzhyzhanovsky strasse 3, 03142 Kiev, Ukraine
Zinaida A. Matysina
Dnepropetrovsk National University, 72 Gagarin strasse, Dnepropetrovsk, 49000 Ukraine
Dmitry Schur
Institute for Problems of Materials Science of NAS of Ukraine, Krzhyzhanovsky strasse 3, 03142 Kiev, Ukraine
Aleksey D. Zolotarenko
Institute for Problems of Materials Science of NAS of Ukraine, Krzhyzhanovsky strasse 3, 03142 Kiev, Ukraine

要約

The theoretical study of fullerene film production on the crystal faces of (100)-type crystals with simple cubic (sc), body-centered cubic (bcc), and face-centered cubic (fcc) lattices is the subject of this paper. The calculation of equilibrium concentration of fullerenes C60, C70 and its dependence on temperature has been carried out. Adsorption-desorption processes of fullerenes on the crystal surface and possible special features of these processes have been investigated. The developed statistical theory of the process of fullerene deposition on the metallic substrate provides an explanation and justification of the possibility of manifestation of these processes, revealing that each is defined to a large extent by the character and degree of interaction between the fullerenes and atoms of the metallic substrate.


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