%0 Journal Article
%A Yadav, Suraj V.
%A Rathod, Virendra K.
%D 2018
%I Begell House
%K artificial enzyme activity, magnetically separable, dopamine-o-quinone, colorimetric detection
%N 4
%P 357-368
%R 10.1615/CatalGreenChemEng.2019029572
%T ENZYME MIMIC OXIDASE-LIKE ACTIVITY OF Fe3O4 MAGNETIC NANOPARTICLES FOR DOPAMINE DETECTION
%U https://www.dl.begellhouse.com/journals/74e300906b6eb358,673e4f21086a75d2,79eaba7b539825a4.html
%V 1
%X Enzyme mimics have garnered substantial attention as they can overcome some severe drawbacks associated with nat-
ural enzymes such as inhibition of their catalytic activity. The present study proves that the Fe3O4 magnetic nanoparticles (MNPs) exhibit an oxidase-like activity similar to that found in the tyrosinase enzyme. The Fe3O4 nanoparticles
(NPs) were prepared by the solvothermal method and characterized by Fourier transform infrared, X-ray diffraction,
scanning electron microscopy with energy dispersive X-ray, X-ray photoelectron spectroscopy (XPS), and dynamic
light scattering/zeta potential techniques to know the structural properties of MNPs. XPS analysis shows that the
enzyme mimetic activity of NPs is due to Fe2+ and Fe3+ in Fe3O4 nanoparticle systems. Colorless dopamine forms
colored dopamine-o-quinone due to surface modification of MNPs as well as both σ- and π-donor bonding contribution
to overall stability. Enzyme mimetics Fe3O4 NPs were used as a new technique for colorimetric detection of dopamine.
%8 2019-01-04