Publicou 6 edições por ano
ISSN Imprimir: 2150-766X
ISSN On-line: 2150-7678
Indexed in
COMBUSTION OF ENERGETIC MATERIALS GOVERNED BY REACTIONS IN THE CONDENSED PHASE
RESUMO
Combustion of energetic materials (EMs) with the leading reaction in the condensed phase is considered. It is assumed that the leading role belongs to the condensed phase not only when the heat flux from the gas to the burning surface is negligibly small, but also in the case of a substantial heat flux, which is consumed for evaporation of unreacted substance. Based on numerous thermocouple-aided experimental studies on combustion of different EMs, it has been shown that the condensed phase can be heated up to its maximum temperature−boiling point−or, in the case of onium salts, dissociation temperature. A microscopic equilibrium at the surface between the boiling substance and vapor rather than a macroscopic one has been supposed to exist that is responsible for the observed surface temperatures. Combustion of AP, ADN, HMX, RDX, and CL-20 is considered here, and resulting kinetic parameters of the leading reactions have been derived from experimental data on the burning rates and surface temperatures, provided burning of these materials follow the condensed-phase combustion model. Using kinetic parameters of the leading reaction and the dependence of the surface temperature on pressure, burning rates of EMs have been simulated in a wide interval of initial temperature and pressure.
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Sinditskii V.P., Egorshev V.Yu., Rudakov G.F., Burzhava A.V., Filatov S.A., Sang L.D., Thermal behavior and combustion mechanism of high-nitrogen energetic materials DHT and BTATz, Thermochimica Acta, 535, 2012. Crossref
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Sinditskii Valery P., Burzhava Anna V., Sheremetev Aleksey B., Aleksandrova Natalia S., Thermal and Combustion Properties of 3,4-Bis(3-nitrofurazan-4-yl)furoxan (DNTF), Propellants, Explosives, Pyrotechnics, 37, 5, 2012. Crossref
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Sinditskii V. P., Chernyi A. N., Marchenkov D. A., Mechanisms of combustion catalysis by ferrocene derivatives. 1. Combustion of ammonium perchlorate and ferrocene, Combustion, Explosion, and Shock Waves, 50, 1, 2014. Crossref
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Jos Jisna, Mathew Suresh, Ammonium Nitrate as an Eco–Friendly Oxidizer for Composite Solid Propellants: Promises and Challenges, Critical Reviews in Solid State and Materials Sciences, 42, 6, 2017. Crossref
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Serushkin Valery V., Sinditskii Valery P., Hoang Trung H., Filatov Sergey A., Shipulina Anna S., Dalinger Igor L., Shakhnes Aleksander Kh., Sheremetev Aleksey B., Thermal and combustion behavior of novel oxygen-rich energetic pyrazoles, Journal of Thermal Analysis and Calorimetry, 132, 1, 2018. Crossref
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Kohga Makoto, Thermal Decomposition Behavior and Burning Characteristics of Ammonium Nitrate/Polytetrahydrofuran Propellants with Glycerol Propoxylate as a Crosslinking Agent, AIAA Propulsion and Energy 2019 Forum, 2019. Crossref
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Kohga Makoto, Togo Shimpei, Catalytic Effect of Added Fe2O3 Amount on Thermal Decomposition Behaviors and Burning Characteristics of Ammonium Nitrate/Ammonium Perchlorate Propellants, Combustion Science and Technology, 192, 9, 2020. Crossref
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Vara Jalpa A., Dave Pragnesh N., Chaturvedi Shalini, The catalytic activity of transition metal oxide nanoparticles on thermal decomposition of ammonium perchlorate, Defence Technology, 15, 4, 2019. Crossref
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Sinditskii Valery P., Smirnova Anastasia D., Serushkin Valery V., Aleksandrova Natali S., Sheremetev Aleksei B., Furazan‐Fused Azacyclic Nitramines: Influence of Structural Features on the Combustion and the Thermolysis, ChemistrySelect, 5, 44, 2020. Crossref
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Sinditskii Valery P., Smirnova Anastasia D., Vu Tuan Q., Filatov Sergey A., Serushkin Valery V., Rudakov Gennady F., Thermal Decomposition of 1,3,5,5‐Tetranitrohexahydro‐Pyrimidine: A New Type of Autocatalysis that Persists at High Temperatures, Propellants, Explosives, Pyrotechnics, 46, 1, 2021. Crossref
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Rudakov Gennady F., Kalinichenko Alexandra I., Nguyen Tu Q., Zinchenko Svetlana S., Cherkaev Georgij V., Fedyanin Ivan V., Sinditskii Valery P., Monosubstituted Polynitroalkoxy‐1,2,4,5‐Tetrazines: A New Family of Melt‐Castable Energetic Materials, Propellants, Explosives, Pyrotechnics, 47, 3, 2022. Crossref