Publicou 4 edições por ano
ISSN Imprimir: 1093-3611
ISSN On-line: 1940-4360
Indexed in
INVESTIGATIONS OF THE ELECTRODEPOSITION OF ALUMINUM-MANGANESE ALLOYS FROM ROOM TEMPERATURE CHLOROALUMINATE MOLTEN SALTS
RESUMO
The electrochemical reduction of manganese (II) in acidic AlCl3:EMIC (aluminum chloride: l-ethyl-3-methylimidazolium chloride) room temperature molten salt results in codeposition of aluminum and manganese. Constant potential deposition in the region of the reduction peak results in the deposition of manganese rich amorphous manganese-aluminum alloys. Constant potential deposition in the region of diffusion control results in the formation of aluminum rich amorphous manganese-aluminum alloys. We have employed an Electrochemical Quartz Crystal Microbalance (EQCM) to investigate, in situ, the deposition and stripping behavior of Al and Al-Mx in acidic AlCl3:EMIC molten salts. The EQCM provides both mass and charge data during electrodeposition and stripping processes. This information can be used to determine codeposited metal composition and to model deposition and/or stripping processes.
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Torimoto Tsukasa, Tsuda Tetsuya, Okazaki Ken-ichi, Kuwabata Susumu, New Frontiers in Materials Science Opened by Ionic Liquids, Advanced Materials, 22, 11, 2010. Crossref
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Tsuda Tetsuya, Arimoto Satoshi, Kuwabata Susumu, Hussey Charles L., Electrodeposition of Al–Mo–Ti Ternary Alloys in the Lewis Acidic Aluminum Chloride–1-Ethyl-3-methylimidazolium Chloride Room-Temperature Ionic Liquid, Journal of The Electrochemical Society, 155, 4, 2008. Crossref
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Tsuda Tetsuya, Kuwabata Susumu, Stafford Gery R., Hussey Charles L., Electrodeposition of aluminum–hafnium alloy from the Lewis acidic aluminum chloride-1-ethyl-3-methylimidazolium chloride molten salt, Journal of Solid State Electrochemistry, 17, 2, 2013. Crossref
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Cross Samuel R., Schuh Christopher A., Ternary alloying additions and multilayering as strategies to enhance the galvanic protection ability of Al-Zn coatings electrodeposited from ionic liquid solution, Electrochimica Acta, 211, 2016. Crossref
-
Sun I-Wen, Chen Po-Yu, Electrodeposition of Alloys, in Electrodeposition from Ionic Liquids, 2017. Crossref
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Tsuda Tetsuya, Stafford Gery R., Hussey Charles L., Review—Electrochemical Surface Finishing and Energy Storage Technology with Room-Temperature Haloaluminate Ionic Liquids and Mixtures, Journal of The Electrochemical Society, 164, 8, 2017. Crossref
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Tsuda Tetsuya, Ikeda Yuichi, Arimura Takashi, Hirogaki Masaki, Imanishi Akihito, Kuwabata Susumu, Stafford Gery R., Hussey Charles L., Electrodeposition of Al-W Alloys in the Lewis Acidic Aluminum Chloride−1-Ethyl-3-Methylimidazolium Chloride Ionic Liquid, Journal of The Electrochemical Society, 161, 9, 2014. Crossref