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Plasma Medicine
SJR: 0.278 SNIP: 0.183 CiteScore™: 0.57

ISSN Imprimir: 1947-5764
ISSN On-line: 1947-5772

Plasma Medicine

DOI: 10.1615/PlasmaMed.2019031459
pages 101-110

Reducing the Toxicity of Tetracycline Solutions and the Kinetics of Decomposition under the Action of DBD in Oxygen

Andrey Gushchin
Department of Industrial Ecology, Ivanovo State University of Chemistry and Technology, Ivanovo, Russia
V. Grinevich
Department of Industrial Ecology, Ivanovo State University of Chemistry and Technology, Ivanovo, Russia
E. Kvitkova
Department of Industrial Ecology, Ivanovo State University of Chemistry and Technology, Ivanovo, Russia
R. Chugunov
Department of Industrial Ecology, Ivanovo State University of Chemistry and Technology, Ivanovo, Russia
T. Izvekova
Department of Industrial Ecology, Ivanovo State University of Chemistry and Technology, Ivanovo, Russia
N.  Kruchinina
Department of Industrial Ecology, Russian State University of Chemical Technology, Moscow, Russia
V. Emzhina
Department of Industrial Ecology, Russian State University of Chemical Technology, Moscow, Russia
N. Ivantsova
Department of Industrial Ecology, Russian State University of Chemical Technology, Moscow, Russia
V. V. Rybkin
Department of Microelectronic Devices and Materials Technology, Ivanovo State University of Chemical Technology, F. Engels ave., 7, Ivanovo, 153000, Russia

RESUMO

The effects of a dielectric barrier discharge (DBD) in oxygen on the kinetics of the decomposition and of product formation of aqueous solutions of tetracycline (THC) were studied. The kinetics of THC decomposition obeyed the first kinetic order, and the degree of decomposition reached 90%. The rate constants and the energy efficiency of the decomposition process were determined. The decomposition products of THC were carboxylic acids, aldehydes, CO, and CO2. The toxic effect of water was determined by the survival rate of freshwater crustaceans Daphnia magna Straus and fish Poecillia reticulata Peters. Treatment with DBD led to a significant reduction in the toxicity of the solutions (by 94.8%).

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