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International Journal of Energetic Materials and Chemical Propulsion

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ISSN Печать: 2150-766X

ISSN Онлайн: 2150-7678

The Impact Factor measures the average number of citations received in a particular year by papers published in the journal during the two preceding years. 2017 Journal Citation Reports (Clarivate Analytics, 2018) IF: 0.7 To calculate the five year Impact Factor, citations are counted in 2017 to the previous five years and divided by the source items published in the previous five years. 2017 Journal Citation Reports (Clarivate Analytics, 2018) 5-Year IF: 0.7 The Immediacy Index is the average number of times an article is cited in the year it is published. The journal Immediacy Index indicates how quickly articles in a journal are cited. Immediacy Index: 0.1 The Eigenfactor score, developed by Jevin West and Carl Bergstrom at the University of Washington, is a rating of the total importance of a scientific journal. Journals are rated according to the number of incoming citations, with citations from highly ranked journals weighted to make a larger contribution to the eigenfactor than those from poorly ranked journals. Eigenfactor: 0.00016 The Journal Citation Indicator (JCI) is a single measurement of the field-normalized citation impact of journals in the Web of Science Core Collection across disciplines. The key words here are that the metric is normalized and cross-disciplinary. JCI: 0.18 SJR: 0.313 SNIP: 0.6 CiteScore™:: 1.6 H-Index: 16

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CONVERSION OF DEMILITARIZED TNT TO HIGHER VALUE PRODUCTS

Том 5, Выпуск 1-6, 2002, pp. 62-70
DOI: 10.1615/IntJEnergeticMaterialsChemProp.v5.i1-6.90
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Краткое описание

The goal of our research is to develop the scientific methodology needed for the chemical conversion of surplus TNT (2,4,6-trinitrotoluene) into higher value products. Although the military use of TNT is well documented, the production of civilian products from TNT is virtually unknown. We now describe some of our results using TNT as a multipurpose raw material for the chemical synthesis of a variety of materials.
Specifically, we have developed more ecologically acceptable conversions of TNT into 2,4,6-triaminotoluene (TAT), 2,4,6-trihydroxytoluene and 2,4,6-triisocyanatotoluene (TICT). In addition, we have studied both the regioselective reductions and regioselective nucleophilic displacements of nitro groups in TNT. We have also converted TNT into a variety of heterocyclic compounds. In summary, our investigations demonstrate that TNT is a versatile building block for the synthesis of new materials ranging from polymers to heterocyclic compounds displaying pharmacological and agrochemical activities.

ЦИТИРОВАНО В
  1. Mezhnev Vasilii V., Dutov Mikhail D., Sapozhnikov Oleg Yu., Kachala Vadim V., Shevelev Svyatoslav A., Synthesis of 5,7-dinitroquinolines from 2,4,6-trinitrotoluene, Mendeleev Communications, 17, 4, 2007. Crossref

  2. Chandrasekhar Batchu, β-Mercaptoalkanoic carboxylic esters: versatile synthons in heterocyclic chemistry, Journal of Sulfur Chemistry, 29, 2, 2008. Crossref

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