Выходит 4 номеров в год
ISSN Печать: 2152-2057
ISSN Онлайн: 2152-2073
IF:
0.2
5-Year IF:
0.3
Eigenfactor:
0.00004
JCI:
0.08
SJR:
0.153
SNIP:
0.178
CiteScore™::
1
H-Index:
12
Indexed in
CRYSTALLIZATION OF DISPERSIVELY FILLED POLYMER NANOCOMPOSITES
Get access
Краткое описание
It is shown that the degree of crystallinity of the polymer matrix on introduction of dispersed nanoparticles is determined by the formation of crystallizing interfacial regions and the melting temperature of crystallites. Aggregation of the initial nanoparticles increases their effectiveness as a nucleating agent for crystallization of the polymer matrix. An increase in the degree of crystallinity of the polymer matrix fully explains the increase in the elasticity modulus in the case of polypropylene/calcium carbonate nanocomposites, and only partially of polypropylene/globular nanocarbon nanocomposites, due to the difference in the crystallization mechanism.
-
Aloev, V.Z. and Kozlov, G.V., The Physics of Orientational Phenomena in Polymeric Materials, Nal'chik: Poligrafservis i T Press, 2002 (in Russian).
-
Balankin, A.S., Synergetics of Deformable Body, Moscow: Voenizdat Press, 1991 (in Russian).
-
Bobryshev, A.N., Kozomazov, V.N., Babin, L.O., and Solomatov, V.I., Synergetics of Composite Materials, Lipetsk, Russia: NPO ORIUS Press, 1994 (in Russian).
-
Budtov, V.P., The Physical Chemistry of Polymer Solutions, St. Petersburg: Khimiya Press, 1992 (in Russian).
-
Deshmane, C., Yuan, Q., and Misra, R.D.K., On the Fracture Characteristics of Impact Tested High Density Polyethylene-Calcium Carbonate Nanocomposites, Mater. Sci. Eng., vols. 452-453A, no. 3, pp. 592-601, 2007.
-
Family, F., Fractal Dimension and Grand Universality of Critical Phenomena, J. Stat. Phys., vol. 36, nos. 5-6, pp. 881-896, 1984.
-
Kalinchev, E.L. and Sakovtseva, M.B., Properties and Processing of Thermoplastics, Leningrad: Khimiya Press, 1983 (in Russian).
-
Kozlov, G.V., Aphashagova, Z.Kh., and Malamatov, A.Kh., The Efficiency of Crystallization Process of Nanocomposites Polyethylene/Calcium Carbonate, Nano Mikrosistem. Tekh., vol. 131, no. 6, pp. 25-27, 2011a (in Russian).
-
Kozlov, G.V., Yanovsky, Y.G., and Zaikov, G.E., Synergetics and Fractal Analysis of Polymer Composites Filled with Short Fibers, New York: Nova Science Publishers, Inc., 2011b.
-
Kozlov, G.V. and Zaikov, G.E., Structure and Properties of Particulate-Filled Polymer Nanocomposites, Saarbrucken, Germany: Lambert Academic Publishing, 2012.
-
Kozlov, G.V. and Zaikov, G.E., Structure of the Polymer Amorphous State, Boston: Brill Academic Publishers, 2004.
-
Mandelkern, L., The Relation Between Structure and Properties of Crystalline Polymers, Polymer J., vol. 17, no. 1, pp. 337-350, 1985.
-
Mikitaev, A.K., Kozlov, G.V., and Zaikov, G.E., Polymer Nanocomposites: Variety of Structural Forms and Applications, Moscow: Nauka Press, 2009 (in Russian).
-
Solomko, V.P., Filled Crystallizing Polymers, Kiev, Ukraine: Naukova Dumka Press, 1980 (in Russian).
-
Tanniru, M. and Misra, R.D.K., On Enhanced Impact Strength of Calcium Carbonate-Reinforced High-Density Polyethylene Composites, Mater. Sci. Eng., vol. 405A, no. 1, pp. 178-193, 2005.
-
Wunderlich, B., Macromolecular Physics. Vol. 2. Crystal Nucleation, Growth, Annealing, New York: Academic Press, 1977.