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Journal of Porous Media
Импакт фактор: 1.49 5-летний Импакт фактор: 1.159 SJR: 0.504 SNIP: 0.671 CiteScore™: 1.58

ISSN Печать: 1091-028X
ISSN Онлайн: 1934-0508

Выпуски:
Том 22, 2019 Том 21, 2018 Том 20, 2017 Том 19, 2016 Том 18, 2015 Том 17, 2014 Том 16, 2013 Том 15, 2012 Том 14, 2011 Том 13, 2010 Том 12, 2009 Том 11, 2008 Том 10, 2007 Том 9, 2006 Том 8, 2005 Том 7, 2004 Том 6, 2003 Том 5, 2002 Том 4, 2001 Том 3, 2000 Том 2, 1999 Том 1, 1998

Journal of Porous Media

DOI: 10.1615/JPorMedia.v13.i4.10
pages 295-305

KINETIC STUDY FOR THE ADSORPTION OF ACATONE AND ETHANOL ON ACTIVATED CARBON

Mhiri Foued
Institut préparatoire aux études d’ingénieur de Monastir
Abdelmajid Jemnia
Laboratoire d'Etude des Systemes Thermiques et Energetiques, Ecole Nationale d'Ingenieurs de Monastir, Tunisia

Краткое описание

Gas adsorption in a microporous solid takes place in three locations: the micropores, the mean pores, and the exterior surface of solid grains. Usually, the mathematical description of the kinetics of such a phenomenon needs a detailed preliminary study of the physical and chemical properties of the adsorbent-adsorbate pair. This article proposes a new mathematical model for the study of the adsorption kinetics. In such a model, the adsorbent-adsorbate system is assumed to be a black box, where we know only the adsorbate instantaneous quantities at the input and the output as well as the used adsorbent mass. This model presents some advantages as it contains only three constants to be determined experimentally. It does not require the chemical and the physical properties of the adsorbent-adsorbate pair, and the phenomenon is described by only one differential equation. This is due to the introduction of two new terms in Tick's law, which are justified by the application conditions of such a law and which are not verified in the case of the gas adsorption in a microporous solid. The first term added is a direct adsorption term corresponding to adsorption in the mean or large pores and to the outward surface. As for the second term, it corresponds to the fluctuation defining the transportation phenomenon presented in classical physics.

Ключевые слова: adsorption, diffusion, fluctuation, Fik's law

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