Доступ предоставлен для: Guest
Портал Begell Электронная Бибилиотека e-Книги Журналы Справочники и Сборники статей Коллекции
Journal of Porous Media
Импакт фактор: 1.49 5-летний Импакт фактор: 1.159 SJR: 0.43 SNIP: 0.671 CiteScore™: 1.58

ISSN Печать: 1091-028X
ISSN Онлайн: 1934-0508

Выпуски:
Том 23, 2020 Том 22, 2019 Том 21, 2018 Том 20, 2017 Том 19, 2016 Том 18, 2015 Том 17, 2014 Том 16, 2013 Том 15, 2012 Том 14, 2011 Том 13, 2010 Том 12, 2009 Том 11, 2008 Том 10, 2007 Том 9, 2006 Том 8, 2005 Том 7, 2004 Том 6, 2003 Том 5, 2002 Том 4, 2001 Том 3, 2000 Том 2, 1999 Том 1, 1998

Journal of Porous Media

DOI: 10.1615/JPorMedia.2019024612
pages 1001-1014

ORGANICS ADSORPTION ON NOVEL AMORPHOUS SILICA AND SILICA XEROGELS: MICROCOLUMN RAPID BREAKTHROUGH TEST COUPLED WITH SEQUENTIAL INJECTION ANALYSIS

Andrea Luca Tasca
Department of Chemical and Process Engineering, University of Strathclyde, Glasgow G1 1XJ, United Kingdom
Ashleigh J. Fletcher
Department of Chemical and Process Engineering, University of Strathclyde, Glasgow G1 1XJ, United Kingdom
Farnaz Ghajeri
Department of Engineering Sciences, Applied Materials Science, Uppsala University, Uppsala, Sweden
Fernando Maya Alejandro
Department of Chemistry, Faculty of Sciences, University of the Balearic Islands, Carretera de Valldemossa km 7.5, E-07122 Palma de Mallorca, Illes Balears, Spain
Gemma Turnes Palomino
Department of Chemistry, Faculty of Sciences, University of the Balearic Islands, Carretera de Valldemossa km 7.5, E-07122 Palma de Mallorca, Illes Balears, Spain

Краткое описание

The adsorption capacities of a novel amorphous silica and silica xerogels for aromatic compounds were investigated using microcolumn rapid breakthrough tests coupled with sequential injection flow-based automated instrumentation in order to evaluate their operative feasibility under conditions typically used in water treatment facilities. Extraction columns were fabricated using stereolithographic 3D printing. Sorbent reusability was also investigated using automated flow-based techniques. Benzene was selected as the target dissolved organic compound usually present in produced waters from the oil and gas sector, continuously increasing. 3,4-Dichloroaniline (3,4-DCA) was selected as part of the endocrine disrupting chemicals, which are becoming a source of major concern for human and wildlife toxicity. Novel amorphous silicas were synthesized at low temperature and under ambient pressure from a sodium metasilicate precursor and were subjected to postsynthetic methylation. Silica xerogels were prepared via acid catalysis of a sodium metasilicate solution and functionalized with trimethylchlorosilane at low temperature and under ambient pressure. The removal efficiency of the silica xerogels tested was found to be equal to or greater than 22.62 mg/g for benzene at a flow rate of 0.6 mL/min, while the uptake of 3,4-DCA was found to be > 4.63 and > 7.17 mg/g, respectively, at flow rates of 1.8 and 0.6 mL/min.

Ключевые слова: SIA, 3, 4-DCA, EDCs, 3D printing, benzene, breakthrough curves

ЛИТЕРАТУРА

  1. Adebajo, M.O., Frost, R.L., Kloprogge, T.J., Carmody, O., and Kokot, S., Porous Materials for Oil Spill Cleanup: A Review of Synthesis and Absorbing Properties, J. Por. Mater., vol. 10, pp. 159-170,2003.

  2. Angioi, S., Polati, S., Roz, M., Rinaudo, C., Gianotti, V., and Gennaro, M.C., Sorption Studies of Chloroanilines on Kaolinite and Montmorillonite, Environ. Pollut, vol. 134, pp. 35-43,2005.

  3. ASTM, Standard Practice for the Prediction of Contaminant Adsorption on GAC in Aqueous Systems Using Rapid Small-Scale Column Tests, ASTM D6586-03, 2008.

  4. Bangi, U.K.H., Rao, A.P., Hirashima, H., and Rao, A.V., Physico-Chemical Properties of Ambiently Dried Sodium Silicate based Aerogels Catalyzed with Various Acids, J. Sol-Gel Sci. Technol., vol. 50, pp. 87-97, 2009.

  5. Barrett, E.P., Joyner, L.G., and Halenda, P.P., The Determination of Pore Volume and Area Distributions in Porous Substances 1: Computations from Nitrogen Isotherms, J. Am. Chem. Soc., vol. 73, pp. 373-380,1951.

  6. Bevan, R., Harrison, P., Youngs, L., Whelan, M., Goslan, E., Macadam, J., Holmes, P., and Persich, T., A Review of Latest Endocrine Disrupting Chemicals Research Implications for Drinking Water, Institute of Environment and Health Rep. DWI:70/2/266, 2012.

  7. Brunauer, S.,Emmett, P.H., and Teller, E., Adsorption of Gases in Multimolecular Layers, J. Am. Chem. Soc, vol. 60, pp. 309-319, 1938.

  8. Chang, Q.G., Zhang, W., Jianga, W.X., Li, B.J., Yinga, W.C., and Lin, W., Efficient Micro Carbon Column Rapid Breakthrough Technique for Water and Wastewater Treatability Studies, Environ. Prog., vol. 26, pp. 280-288, 2007.

  9. Economou, A., Sequential-Injection Analysis (SIA): A Useful Tool for On-line Sample-Handling and Pre-Treatment, TrAC Trends Anal. Chem, vol. 24, pp. 416-425,2005.

  10. Falkova, M., Vakh, C., Shishov, A., Zubakina, E., Moskvin, A., Moskvin, L., and Bulatov, A., Automated IR Determination of Petroleum Products in Water based on Sequential Injection Analysis, Talanta, vol. 148, pp. 661-665, 2016.

  11. Freundlich, H. and Hatfield, H., Colloid and Capillary Chemistry, London: Methuen, 1926.

  12. Hampson, S.M., Rowe, W., Christie, S.D.R., and Platt, M., 3D Printed Microfluidic Device with Integrated Optical Sensing for Particle Analysis, Sens. Actuator B-Chem., vol. 256, pp. 1030-1037, 2018.

  13. Hwa, L.C., Rajoo, S., Noor, A.M., Ahmad, N., andUday, M.B., Recent Advances in 3D Printing of Porous Ceramics: A Review, Curr. Opin. Solid State Mater. Sci, vol. 21, pp. 323-347,2017.

  14. Kortenkamp, A., Faust, M., Scholze, M., and Backhaus, T., Low-Level Exposure to Multiple Chemicals: Reason for Human Health Concerns?, Environ. Health Perspect., vol. 115, pp. 106-114, 2007.

  15. Lee, J.W., Lee, J.W., Shim, W.G., Suh, S.H., and Moon, H., Adsorption of Chlorinated Volatile Organic Compounds on MCM-48, J. Chem. Eng. Data, vol. 48, pp. 381-387, 2003.

  16. Maretto, M., Bianchi, F., Vignola, R., Canepari, S., Baric, M., Iazzoni, R., Tagliabue, M., and Papini, M.P., Microporous and Mesoporous Materials for the Treatment of Wastewater Produced by Petrochemical Activities, J. Clean. Prod., vol. 77, pp. 22-34, 2014.

  17. Mitsouras, D., Liacouras, P., Imanzadeh, A., Giannopoulos, A.A., Cai, T.R., Kumamaru, K.K., George, E., Wake, N., Caterson, E.J., Pomahac, B., Ho, V.B., Grant, G.T., and Rybicki, F.J., Medical 3D Printing for the Radiologist, Radiographics, vol. 35, pp. 1966-1989,2015.

  18. Olalekan, A.P., Dada, A.O., and Adesina, O.A., Review: Silica Aerogel as a Viable Absorbent for Oil Spill Remediation, J. Encapsul. Adsorp. Sci., vol. 4, pp. 122-131, 2014.

  19. Perdigoto, M.L.N., Martins, R.C., Rocha, N., Quina, M.J., Gando-Ferreira, L., Patricio, R., and Duraes, L., Application of Hydrophobic Silica based Aerogels and Xerogels for Removal of Toxic Organic Compounds from Aqueous Solutions, J. Colloid Interface Sci., vol. 380, pp. 134-140, 2012.

  20. Reynolds, J.G., Coronado, P.R., and Hrubesh, L.W., Hydrophobic Aerogels for Oil-Spill Clean Up - Synthesis and Characterization, J. Non-Crystal. Solids, vol. 292, pp. 127-137, 2001a.

  21. Reynolds, J.G., Coronado, P.R., and Hrubesh, L.W., Hydrophobic Aerogels for Oil-Spill Cleanup - Intrinsic Absorbing Properties, Energy Sources, vol. 23, pp. 831-843,2001b.

  22. Rodriguez, R., Avivar, J., Leal, L.O., Cerda, V., and Ferrer, L., Strategies for Automating Solid-Phase Extraction and Liquid-Liquid Extraction in Radiochemical Analysis, TrAC, Trends Anal. Chem., vol. 76, pp. 145-152,2016.

  23. Shu, H.C. and Chung, S.W., Analysis of Organophosphorous Pesticides based on Housefly Acetylcholinesterase Using Sequential Injection Analysis, J. Chin. Chem. Soc., vol. 64, pp. 1460-1466, 2017.

  24. Simpson, E.J., Abukhadra, R.K., Koros, W.J., and Schechter, R.S., Sorption Equilibrium Isotherms for Volatile Organics in Aqueous-Solution - Comparison of Headspace Gas-Chromatography and Online UV Stirred Cell Results, Ind. Eng. Chem. Res., vol. 32, pp. 2269-2276, 1993.

  25. Szczepanik, B., Slomkiewicz, P., Garnuszek, M., and Czech, K., Adsorption of Chloroanilines from Aqueous Solutions on the Modified Halloysite, Appl. Clay Sci, vol. 101, pp. 260-264, 2014.

  26. Tasca, A.L., Ghajeri, F., and Fletcher, A.J., Novel Hydrophilic and Hydrophobic Amorphous Silica: Characterization and Adsorption of Aqueous Phase Organic Compounds, Adsorpt. Sci. Technol., vol. 36, pp. 327-342, 2017.

  27. Turiel, E., Perez-Conde, C., and Martin-Esteban, A., Assessment of the Cross-Reactivity and Binding Sites Characterisation of a Propazine-Imprinted Polymer Using the Langmuir-Freundlich Isotherm, Analyst, vol. 128, pp. 137-141, 2003.

  28. Twumasi Afriyie, E., Karami, P., Norberg, P., and Gudmundsson, K., Textural and Thermal Conductivity Properties of a Low Density Mesoporous Silica Material, Energy Build., vol. 75, pp. 210-215,2014.

  29. Twumasi Afriyie, E., Norberg, P., Sjostrom, C., and Forslund, M., Preparation and Characterization of Double Metal-Silica Sorbent for Gas Filtration, Adsorption, vol. 19, pp. 49-61, 2013.

  30. Wang, D., Mclaughlin, E., Pfeffer, R., and Lin, J.Y.S., Adsorption of Organic Compounds in Vapor, Liquid, and Aqueous Solution Phases on Hydrophobic Aerogels, Ind. Eng. Chem. Res., vol. 50, pp. 12177-12185,2011.

  31. Wang, D., Mclaughlin, E., Pfeffer, R., and Lin, J.Y.S., Adsorption of Oils from Pure Liquid and Oil-Water Emulsion on Hydrophobic Silica Aerogels, Sep. Purif. Technol, vol. 99, pp. 28-35, 2012.

  32. Ying, W.C., Zhang, W., Chang, Q.G., Jiang, W.X., and Li, G.H., Improved Methods for Carbon Adsorption Studies for Water and Wastewater Treatment, Environ. Prog, vol. 25, pp. 110-120, 2006.


Articles with similar content:

PREPARATION OF COMBI-MAGNETIC CROSS-LINKED ENZYME AGGREGATES OF CELLULASE AND LIPASE
Catalysis in Green Chemistry and Engineering, Vol.1, 2018, issue 4
Virendra K. Rathod, Girish S. Nhivekar
DYNAMIC CHARACTERIZATION OF ADSORPTION IN METAL HYDRIDES
ICHMT DIGITAL LIBRARY ONLINE, Vol.0, 2009, issue
C. Sobrinho, Joao Luis Toste Azevedo, N. Santos
MICROREACTORS FOR BIODIESEL SYNTHESIS: DESIGN, FABRICATION, AND CHARACTERIZATION
Heat Pipe Science and Technology, An International Journal, Vol.6, 2015, issue 3-4
Christopher P. Tostado, Jose Martim Costa, Jr., Jeziel S. Nunes, Carolina Palma Naveira-Cotta
SYNTHESIS OF HYDROPHOBIC COATING USING A SOL−GEL PYROLYTIC SPRAY COATING SYSTEM
Nanoscience and Technology: An International Journal, Vol.10, 2019, issue 3
Tamchek Nizam, Che Ibrahim Mohd Naqiudin, Tazuri Mohd Syafiq
EXPERIMENTAL INVESTIGATIONS ON AIR GASIFICATION OF COFFEE HUSK
Proceedings of the 24th National and 2nd International ISHMT-ASTFE Heat and Mass Transfer Conference (IHMTC-2017), Vol.0, 2017, issue
Joel George, P. Arun, C. Muraleedharan