Доступ предоставлен для: Guest
Портал Begell Электронная Бибилиотека e-Книги Журналы Справочники и Сборники статей Коллекции
Plasma Medicine
SJR: 0.271 SNIP: 0.316 CiteScore™: 1.9

ISSN Печать: 1947-5764
ISSN Онлайн: 1947-5772

Plasma Medicine

DOI: 10.1615/PlasmaMed.2020034060
pages 61-69

Development of Niobium Based Coatings Prepared by Ion-Plasma Vacuum-Arc Deposition

V. S. Taran
National Science Center "Kharkiv Institute of Physics and Technology" (NSC KIPT), Institute of Plasma Physics, Kharkiv, Ukraine
I. E. Garkusha
National Science Center "Kharkiv Institute of Physics and Technology" (NSC KIPT), Institute of Plasma Physics, Kharkiv, Ukraine; V.N. Karazin Kharkiv National University, Kharkiv, Ukraine
O. I. Tymoshenko
National Science Center "Kharkiv Institute of Physics and Technology" (NSC KIPT), Institute of Plasma Physics, Kharkiv, Ukraine
A. V. Taran
National Science Center "Kharkiv Institute of Physics and Technology" (NSC KIPT), Institute of Plasma Physics, Kharkiv, Ukraine
Ivan O. Misiruk
National Science Center "Kharkiv Institute of Physics and Technology" (NSC KIPT), Institute of Plasma Physics, Kharkiv, Ukraine
T. S. Skoblo
Kharkiv Petro Vasylenko National Technical University of Agriculture, Kharkiv, Ukraine
S. P. Romaniuk
Kharkiv Petro Vasylenko National Technical University of Agriculture, Kharkiv, Ukraine
V. V. Starikov
National Technical University "Kharkiv Polytechnic Institute", Kharkiv, Ukraine
A. A. Baturin
National Technical University "Kharkiv Polytechnic Institute", Kharkiv, Ukraine
G. P. Nikolaychuk
National Technical University, Kharkiv Polytechnic Institute, Kharkiv, Ukraine

Краткое описание

Comparative studies of niobium carbide and niobium carbonitride coatings deposited on AISI 430 stainless steel have been presented. The NbC and NbCN coatings have been deposited by vacuum-arc evaporation in Bulat-type device by using the pulsed biasing mode with repetition frequency 50 kHz, allowing decreasing the micro-arcs formation. An additional magnetic coil for plasma flow focusing was used, allowing one to enhance deposition rate up to 35 µm/h. The phase composition of the obtained coatings was analyzed via X-ray diffraction. The surface morphology was monitored by scanning electron microscopy; whereas, chemical composition was examined by using energy dispersive X-ray analysis. X-ray fluorescent analysis was used to evaluate the thickness of the coatings. The reflectance R(λ) of the obtained coatings in the wavelength 300−625 nm at normal incidence was measured. The XRD data from NbC coating revealed the existence of the niobium carbide phase with a NaCl-type lattice with fine-crystalline grains ranging from 14 to 16 nm. For the NbCN coating, the two-phase state with c-NbC and hexagonal NbN0.95 phases was monitored. The average grain size for c-NbC phase comprised 16−17 nm; whereas, for NbN0.95 the average grain size was only 1−2 nm, confirming formation of a nanocrystalline structure. Surface nanomechanical behavior under nanoindentation of NbC and NbCN was studied. It was revealed that nanohardness for a NbC coating was varied from 30 to 43 GPa; whereas, for NbCN the data spread comprised 30−48 GPa. It was established that the surface of the grown coatings was very smooth with an extremely low amount of macroparticles.

ЛИТЕРАТУРА

  1. Ramirez G, Rodil SE, Arzate H, Muhl S, Olaya JJ. Niobium based coatings for dental implants. Appl Surf Sc. 2011;257(7):2555-9.

  2. Shi J, Zhang X, Qiao S, Ni J, Mo J, Gu Y, La H. Enhanced osteointegration of tantalum-modified titanium implants with micro/nano-topography. RSC Adv. 2017;7:46472-9.

  3. Okazaki Y, Ito Y, Ito A, Tateishi T. Effect of alloying elements on mechanical properties of titanium alloys for medical implants. Mater Trans JIM. 1993;34:1217-22.

  4. Okazaki Y, Rao S, Tateishi T, Ito Y. Cytocompatibility of various metals and development of new titanium alloys for medical implants. Mater Sci Eng A. 1998;243(1-2):250-6.

  5. Maya AEA, Grana DR, Hazarabedian A, Kokubu GA, Luppo MI, Vigna G. Zr-Ti-Nb porous alloys for biomedical application. Mater Sci Eng C. 2012;32(2):321-9.

  6. Braic M, Braic V, Balaceanu M, Vladescu A, Zoita CN, Titorencu I, Jing V. Preparation and characterization of biocompatible Nb-C coatings. Thin Solid Films. 2011;519(12):4064-8.

  7. Matsuno H, Yokoyama A, Watari F, Uo M, Kawasaki T. Biocompatibility and osteogenesis of refractory metal implants, titanium, hafnium, niobium, tantalum and rhenium. Biomaterials. 2001;22:1253-62.

  8. Cuppari MGV, Santos SF. Physical properties of the NbC carbide. Metals. 2016;6(10):250.

  9. Han MK, Kim JY, Hwang MJ, Song HJ, Park YJ. Effect of Nb on the microstructure, mechanical properties, corrosion behavior, and cytotoxicity of Ti-Nb alloys. Materials. 2015;8(9):5986-6003.

  10. Guzmana P, Caballeroa JL, Orozco-Hernandezb G, Aperadora W, Caicedo JC. Tribocorrosion behavior of niobium-based thin films for biomedical applications. Tribol Indust. 2018;40(4):624-32.

  11. Xu Z, Yate L, Qiu Y, Aperador W, Coy E, Jiang B, Moya S, Wang G, Pan H. Potential of niobium-based thin films as a protective and osteogenic coating for dental implants: The role of the nonmetal elements. Mat Sci Eng C. 2019;96:166-75.

  12. Venkataraj S, Drese R, Kappertz O, Jayavel R, Wuttig M. Characterization of niobium oxide films prepared by reactive DC magnetron sputtering. Phys Status Solidi A. 2001;188:1047-58.

  13. Taran AV, Garkusha IE, Taran VS, Muratov RM. Anti-corrosion ceramic coatings on the surface of Nd-Fe-B repelling magnets. Probl Atom Sci Technol. 2019;25(1):116-9.

  14. Cullity DB. Elements of x-ray diffraction. 2nd ed. Boston: Addison Wesley; 1978.


Articles with similar content:

PROCESS OF FORMATION OF SPHEROIDAL GOLD PARTICLES AND OF NANOPHASES IN AlN−TiB2−TiSi2 COATINGS AFTER ANNEALING WITH SUBSEQUENT IMPLANTATION
High Temperature Material Processes: An International Quarterly of High-Technology Plasma Processes, Vol.19, 2015, issue 2
Katerina Smyrnova, Konrad Kierczynski, Yoshihiko Takeda, Anatoliy Kupchishin, Henryk Komsta, Hiroshi Amekura, Marek Opielak, Bahyt Zhollybekov, Artem Demianenko
PRODUCTION AND CHARACTERIZATION OF CA-PVD ZrN AND ZrCN COATINGS ON AISI D3 HIGH-CARBON TOOL STEEL
High Temperature Material Processes: An International Quarterly of High-Technology Plasma Processes, Vol.24, 2020, issue 2
Ivan O. Misiruk, S. P. Romaniuk, A. V. Taran, I. E. Garkusha, V. S. Taran, T. V. Mal’tsev, O. I. Tymoshenko, T. S. Skoblo
HYDROGEN ABSORPTION-DESORPTION IN LaMg2Ni
HYSYDAYS
1st World Congress of Young Scientists on Hydrogen Energy Systems, Vol.0, 2005, issue
A. Ziggiotti, G. Cocco, M. Di Chio, M. Baricco, S. Enzo, L. Schiffini
THE INFLUENCE OF COPPER ON MICROSTRUCTURE AND CATALYTIC PROPERTIES OF CEO2 THIN FILMS DEPOSITED BY PULSED LASER DEPOSITION
High Temperature Material Processes: An International Quarterly of High-Technology Plasma Processes, Vol.7, 2003, issue 3
Ch. Leroux, J. R. Gavarri, R. Chmielowski, A. Kopia, S. Villain, J. Kusinski, S. Saiztek, M. Klimczak-Chmielowska
PARAMETERS OF CHEMICAL VAPOR DEPOSITION ON A STRUCTURE AND THE PROPERTIES OF NANOSTRUCTURED TaC COATING ON A CARBON COMPOSITE MATERIAL
Nanoscience and Technology: An International Journal, Vol.5, 2014, issue 3
K. Chuprunov, A. Yudin, V. N. Anikin, Denis Leybo, S. A. Eremin, I. N. Burmistrov, D. V. Kuznetsov