Доступ предоставлен для: Guest
Catalysis in Green Chemistry and Engineering

Выходит 4 номеров в год

ISSN Печать: 2572-9896

ISSN Онлайн: 2572-990X

H-Index: 2

Indexed in

DUAL APPLICATION OF DIVALENT ION-ANCHORED CATALYST: BIODIESEL SYNTHESIS AND PHOTOCATALYTIC DEGRADATION OF CARBAMAZEPINE

Том 2, Выпуск 1, 2019, pp. 25-42
DOI: 10.1615/CatalGreenChemEng.2019030878
Get accessGet access

Краткое описание

The present work comprises the investigation of the effect of strontium and barium ion-based catalysts on biodiesel production from linseed oil and on the degradation of emerging pollutant carbamazepine (CBZ). The characterization of the synthesized catalyst was done using Fourier transform infrared spectroscopy, scanning electron microscopy, X-ray diffraction (XRD), transmission electron microscopy, Brunauer-Emmett-Teller (BET) analysis, and X-ray photoelectron spectroscopy. XRD patterns suggested the highly crystalline nature of both catalysts. The BET surface areas of the strontium-based catalyst (SBC) and barium-based catalyst (BBC) were 0.139 and 0.142 m2/g, respectively. Linseedoil-derived biodiesel was characterized by gas chromatography with mass spectrometry (GC-MS), 1H and 13C nuclear magnetic resonance. The maximum yields of 96.13% and 94.41% of linseed oil methyl ester were observed with 0.8 wt % BBC and 1.2 wt % SBC, respectively, at 60°C within a reaction time of 120 min. The physical properties of synthesized biodiesel from linseed oil were determined by the EN 14214 method. The efficiency of UV-assisted photocatalytic degradation of CBZ using SBC and BBC as a catalyst was determined. The 98.5% and 94.5% degradation of CBZ were achieved with BBC and SBC, respectively, with an oxidant dose of 20 mM at their optimum pH. The identification of the obtained degraded products was done by GC-MS analysis, which showed the formation of four by-products, viz., iminostilbene, benzoic acid 4-ethoxy- ethyl ester, ethyl 3-hydroxybenzoate, and isophthalaldehyde. Synthesized catalysts were found to be efficient in biodiesel synthesis and photocatalytic degradation of CBZ.

ЛИТЕРАТУРА
  1. Abbah, E.C., Nwandikom, G.I., Egwuonwu, C.C., and Nwakuba, N.R., Effect of Reaction Temperature on the Yield of Biodiesel from Neem Seed Oil, Am. J. Energy Sci., vol. 3, no. 3, pp. 16-20, 2016.

  2. Aleme, H.G. and Barbeira, P.J.S., Determination of Flash Point and Cetane Index in Diesel Using Distillation Curves and Multivariate Calibration, Fuel, vol. 102, pp. 129-134,2012.

  3. Ambat, I., Srivastava, V., and Sillanpaa, M., Recent Advancement in Biodiesel Production Methodologies Using Various Feedstock: A Review, Renew. Sustain. Energy Rev., vol. 90, pp. 356-369, 2018a.

  4. Ambat, I., Srivastava, V., Haapaniemi, E., and Sillanpaa, M., Application of Potassium Ion Impregnated Titanium Dioxide as Nanocatalyst for Transesterification of Linseed Oil, Energy Fuels, vol. 32, pp. 11645-11655,2018b.

  5. Ambat, I., Srivastava, V., Haapaniemi, E., and Sillanpaa, M., Nano-Magnetic Potassium Impregnated Ceria as Catalyst for the Biodiesel Production, Renew. Energy, vol. 139, pp. 1428-1436, 2019.

  6. Aransiola, E.F., Ojumu, T.V., Oyekola, O.O., Madzimbamuto, T.F., and Ikhu-Omoregbe, D.I.O., A Review of Current Technology for Biodiesel Production: State of the Art, Biomass Bioenergy, vol. 61, pp. 276-297, 2014.

  7. Banihani, F.F., Transesterification and Production of Biodiesel from Waste Cooking Oil: Effect of Operation Variables on Fuel Properties, Amer. J. Chem. Eng., vol. 4, no. 6, pp. 154-160,2016.

  8. Basahel, S.N., Ali, T.T., Mokhtar, M., and Narasimharao, K., Influence of Crystal Structure ofNanosizedZrO2 on Photocatalytic Degradation of Methyl Orange, Nanoscale Res. Lett., vol. 10, no. 73, 2015. DOI: 10.1186/s11671-015-0780-z.

  9. Baskar, G., Selvakumari, I.A.E., and Aiswarya, R., Biodiesel Production from Castor Oil Using Heterogeneous Ni Doped ZnO Nanocatalyst, Bioresour. Technol., vol. 250, pp. 793-798, 2018.

  10. Ben, S., Zhao, F., Safaei, Z., Babu, I., Lakshmi, D., and Sillanpaa, M., Reactivity of Novel Ceria-Perovskite Composites CeO2- LaMO3 (MCu, Fe) in the Catalytic Wet Peroxidative Oxidation of the New Emergent Pollutant 'Bisphenol F': Characterization, Kinetic and Mechanism Studies, Appl. Catal. B: Environ, vol. 218, pp. 119-136, 2017.

  11. Bet-Moushoul, E., Farhadi, K., Mansourpanah, Y., Nikbakht, A.M., Molaei, R., and Forough, M., Application of CaO-Based/Au Nanoparticles as Heterogeneous Nanocatalysts in Biodiesel Production, Fuel, vol. 164, pp. 119-127,2016.

  12. Chhetri, A.B., Watts, K.C., and Islam, M.R., Waste Cooking Oil as an Alternate Feedstock for Biodiesel Production, Energies, vol. 1,pp. 3-18, 2008.

  13. Dai, C., Zhou, X., Zhang, Y., Duan, Y., Qiang, Z., and Zhang, T.C., Comparative Study of the Degradation of Carbamazepine in Water by Advanced Oxidation Processes, Environ. Technol., vol. 33, no. 10, pp. 1101-1109, 2012.

  14. Ding, H., Ye, W., Wang, Y., Wang, X., Li, L., Liu, D., Gui, J., Song, C., and Ji, N., Process Intensification of Transesterification for Biodiesel Production from Palm Oil: Microwave Irradiation on Transesterification Reaction Catalyzed by Acidic Imidazolium Ionic Liquids, Energy, vol. 144, pp. 957-967,2018.

  15. Eevera, T., Rajendran, K., and Saradha, S., Biodiesel Production Process Optimization and Characterization to Assess the Suitability of the Product for Varied Environmental Conditions, Renew. Energy, vol. 34, pp. 762-765, 2009.

  16. Encinar, J.M., Pardal, A., and Sanchez, N., An Improvement to the Transesterification Process by the Use of Co-Solvents to Produce Biodiesel, Fuel, vol. 166, pp. 51-58, 2016.

  17. Ezekannagha, C.B., Ude, C.N., and Onukwuli, O.D., Optimization of the Methanolysis of Lard Oil in the Production of Biodiesel with Response Surface Methodology, Egypt. J. Pet., vol. 26, no. 4, pp. 1001-1011,2017.

  18. Faungnawakij, K., Yoosuk, B., and Namuangruk, S., Sr-Mg Mixed Oxides as Biodiesel Production Catalysts, ChemCatChem, vol. 4, pp. 209-216,2012.

  19. Fetisov, A.V., Kozhina, G.A., Estemirova, S.K., Fetisov, V.B., Mitrofanov, V.Y., Uporov, S.A., and Vedmid, L.B., XPS Study of Mechanically Activated YBa2Cu3O6+s andNdBa2Cu3O6+s, J. Spectroscopy, 2013. DOI: 10.1155/2013/217268.

  20. Fu, L., Liu, X., Zhang, Y., Dravid, V.P., and Mirkin, C.A., Nanopatterning of "Hard" Magnetic Nanostructures via Dip-Pen Nano- lithography and a Sol-Based Ink, Nano Lett., vol. 3, no. 6, pp. 757-760, 2003.

  21. Galvan, G., Romero, R., Ramirez, A., Luz, S., Baeza-Jimenez, R., and Natividad, R., Biodiesel Production from Used Cooking Oil and Sea Sand as Heterogeneous Catalyst, Fuel, vol. 138, pp. 143-148, 2014.

  22. Garcia-Espinoza, D., Mijaylova-Nacheva, P., and Avil, M., Electrochemical Carbamazepine Degradation: Effect of the Generated Active Chlorine, Transformation Pathways and Toxicity, Chemosphere, vol. 192, pp. 142-151, 2018.

  23. Gurung, K., Chaker, M., Shestakova, M., and Sillanpaa, M., Removal of Carbamazepine from MBR Effluent by Electrochemical Oxidation, Appl. Catal. B: Environ, vol. 221, pp. 329-338, 2018.

  24. Huang, G., Chen, F., Wei, D., Zhang, X., and Chen, G., Biodiesel Production by Microalgal Biotechnology, Appl. Energy, vol. 87, pp. 38-46,2010.

  25. Iftekhar, S., Srivastava, V., and Casas, A., Synthesis of Novel GA-g-PAM/SiO2 Nanocomposite for the Recovery of Rare Earth Elements (REE) Ions from Aqueous Solution, J. Cleaner Prod, vol. 170, pp. 251-259, 2018.

  26. Im, J., Son, H., Kang, Y., and Zoh, K., Carbamazepine Degradation by Photolysis and Titanium Dioxide Photocatalysis, Water Environ. Res., vol. 84, pp. 554-561, 2019.

  27. Kafui, G., Sunnu, A., and Parbey, J., Effect of Biodiesel Production Parameters on Viscosity and Yield of Methyl Esters: Jatropha Curcas, Elaeis Guineensis and Cocos Nucifera, Alexandria Eng. J., vol. 54, pp. 1285-1290,2015.

  28. Keen, O.S., Baik, S., Linden, K.G., Aga, D.S., and Love, N.G., Enhanced Biodegradation of Carbamazepine after UV/H2O2 Advanced Oxidation, Environ. Sci. Technol, vol. 46, pp. 6222-6227, 2012.

  29. Kumar, P., Kaur, R., Verma, S., Srivastava, V.C., and Mishra, I.M., The Preparation and Efficacy of SrO/CeO2 Catalysts for the Production of Dimethyl Carbonate by Transesterification of Ethylene Carbonate, Fuel, vol. 220, pp. 706-716,2018.

  30. Li, J., Dodgen, L., Ye, Q., and Gan, J., Degradation Kinetics and Metabolites of Carbamazepine in Soil, Environ. Sci. Technol., vol. 47, pp. 3678-3684,2013.

  31. Madhuvilakku, R. and Piraman, S., Biodiesel Synthesis by TiO2-ZnO Mixed Oxide Nanocatalyst Catalyzed Palm Oil Transesteri- fication Process, Bioresour. Technol, vol. 150, pp. 55-59, 2013.

  32. Mello, V.M., Oliveira, F.C.C., Fraga, W.G., Claudia, J., and Suarez, P.A.Z., Determination of the Content of Fatty Acid Methyl Esters (FAME) in Biodiesel Samples Obtained by Esterification Using 1 H-NMR Spectroscopy, Magn. Reson. Chem., vol. 46, pp. 1051-1054,2008.

  33. Nerantzaki, M. and Filippousi, M., Novel Poly (Butylene Succinate) Nanocomposites Containing Strontium Hydroxyapatite Nanorods with Enhanced Osteoconductivity for Tissue Engineering Applications, eXPRESS Polym. Lett., vol. 9, no. 9, pp. 773-789,2015.

  34. Rodriguez-Cruz, S.E., Jockusch, R.A., and Williams, E.R., Binding Energies of Hexahydrated Alkaline Earth Metal Ions, M2+(H2O)6, M = Mg, Ca, Sr, Ba: Evidence of Isomeric Structures for Magnesium, J. Amer. Chem. Soc., vol. 121, pp. 1986-1987,1999.

  35. Shimada, S., Hiroi, T., Ida, T., Mizuno, M., Endo, K., Kurmaev, E.Z., and Moewes, A., X-Ray Photoelectron and Carbon Ka Emission Measurements and Calculations of O- , CO-, N-, and S-Containing Substances, Wiley InterScience, accessed Sept. 1, 2018, from www.interscience.wiley.com, 2006.

  36. Singh, V., Bux, F., and Sharma, Y.C., A Low Cost One Pot Synthesis of Biodiesel from Waste Frying Oil (WFO) Using a Novel Material, (3-Potassium Dizirconate (I3-K2Zr2O5), Appl. Energy, vol. 172, pp. 23-33, 2016.

  37. Sivakumar, P.M., Nanostructure, Nanosystems, and Nanostructured Materials: Theory, Production and Development, Oakville, Ontario: Apple Academic Press, 2014.

  38. Srivastava, V., Kohout, T., and Sillanpaa, M., Potential of Cobalt Ferrite Nanoparticles (CoFe2 O4) for Remediation of Hexavalent Chromium from Synthetic and Printing Press Wastewater, J. Environ. Chem. Eng., vol. 4, pp. 2922-2932, 2016.

  39. Takase, M., Chen, Y., Liu, H., Zhao, T., Yang, L., and Wu, X., Biodiesel Production from Non-Edible Silybum Marianum Oil Using Heterogeneous Solid Base Catalyst under Ultrasonication, Ultrason. Sonochem., vol. 21, pp. 1752-1762, 2014.

  40. Tariq, M., Ali, S., Ahmad, F., Ahmad, M., Zafar, M., Khalid, N., and Khan, M.A., Identification, FT-IR, NMR (1H and 13C) and GC/MS Studies of Fatty Acid Methyl Esters in Biodiesel from Rocket Seed Oil, Fuel Process. Technol, vol. 92, pp. 336-341, 2011.

  41. Teo, S.H., Islam, A., and Taufiq-Yap, Y.H., Algae Derived Biodiesel Using Nanocatalytic Transesterification Process, Chem. Eng. Res. Des, vol. 111, pp. 362-370, 2016.

  42. Thangaraj, B. and Piraman, S., Heteropoly Acid Coated ZnO Nanocatalyst for Madhuca Indica Biodiesel Synthesis, Biofuels, vol. 7, pp. 13-20,2016.

  43. Thanekar, P., Panda, M., and Gogate, P.R., Degradation of Carbamazepine Using Hydrodynamic Cavitation Combined with Advanced Oxidation Processes, Ultrason. Sonochemi., vol. 40, pp. 567-576,2018.

  44. Thushari, I. and Babel, S., Sustainable Utilization of Waste Palm Oil and Sulfonated Carbon Catalyst Derived from Coconut Meal Residue for Biodiesel Production, Bioresour. Technol., vol. 248, pp. 199-203, 2018.

  45. Tipcompor, N., Thongtem, T., Phuruangrat, A., and Thongtem, S., Characterization of SrCO3 and BaCO3 Nanoparticles Synthesized by Cyclic Microwave Radiation, Mater. Lett:., vol. 87, pp. 153-156, 2012.

  46. Todera, M.S., Filip, S., and Ardelean, I., Structural Study of the Fe2O3-B2O3-BaO Glass System by FTIR Spectroscopy, J. Opto-electron. Adv. Mater, vol. 8, no. 3, pp. 1121-1123,2006.

  47. Vedrine, J.C. and Korotchekov, G., Eds., Metal Oxides Series, Amsterdam: Elsevier, 2018.

  48. Wang, M., Han, J., Hu, Y., and Guo, R., Mesoporous C, N-Codoped TiO2 Hybrid Shells with Enhanced Visible Light Photocatalytic Performance, RSC Adv., vol. 7, pp. 15513-15520,2017.

  49. Wang, Z., Srivastava, V., Iftekhar, S., Ambat, I., and Sillanpaa, M., Fabrication of Sb2O3/PbO Photocatalyst for the UV/PMS Assisted Degradation of Carbamazepine from Synthetic Wastewater, Chem. Eng. J., vol. 354, pp. 663-671, 2018.

  50. Wen, L., Wang, Y., Lu, D., Hu, S., and Han, H., Preparation of KF/CaO Nanocatalyst and Its Application in Biodiesel Production from Chinese Tallow Seed Oil, Fuel, vol. 89, pp. 2267-2271, 2010.

  51. Yu, E. and Kuznetsov, M.V., Fluctuation of Surface Composition and Chemical States at the Hetero-Interface in Composites Comprised of a Phase with Perovskite Structure and a Phase Related to the Ruddlesden-Popper Family of Compounds, RSC Adv., vol. 3, pp. 14114-14122, 2013.

  52. Zhang, Y., GeiBen, S., and Gal, C., Carbamazepine and Diclofenac: Removal in Wastewater Treatment Plants and Occurrence in Water Bodies, Chemosphere, vol. 73,pp. 1151-1161,2008.

  53. Zhou, S.,Xia, Y.,Li, T., Yao, T., Shi, Z., andZhu, S., Degradation of Carbamazepine by UV/Chlorine Advanced Oxidation Process and Formation of Disinfection By-Products, Environ. Sci. Pollut. Res., vol. 23, pp. 16448-16455, 2016.

ЦИТИРОВАНО В
  1. Ambat Indu, Srivastava Varsha, Haapaniemi Esa, Sillanpää Mika, Novel Functionality of Lithium-Impregnated Titania as Nanocatalyst, Catalysts, 9, 11, 2019. Crossref

  2. Ambat Indu, Bec Sabina, Peltomaa Elina, Srivastava Varsha, Ojala Anne, Sillanpää Mika, A synergic approach for nutrient recovery and biodiesel production by the cultivation of microalga species in the fertilizer plant wastewater, Scientific Reports, 9, 1, 2019. Crossref

  3. Zare Ehsan Nazarzadeh, Iftekhar Sidra, Park Yuri, Joseph Jessy, Srivastava Varsha, Khan Moonis Ali, Makvandi Pooyan, Sillanpaa Mika, Varma Rajender S., An overview on non-spherical semiconductors for heterogeneous photocatalytic degradation of organic water contaminants, Chemosphere, 280, 2021. Crossref

  4. Srivastava Varsha, Zare Ehsan Nazarzadeh, Makvandi Pooyan, Zheng Xuan-qi, Iftekhar Sidra, Wu Aimin, Padil Vinod V.T., Mokhtari Babak, Varma Rajender S., Tay Franklin R., Sillanpaa Mika, Cytotoxic aquatic pollutants and their removal by nanocomposite-based sorbents, Chemosphere, 258, 2020. Crossref

Портал Begell Электронная Бибилиотека e-Книги Журналы Справочники и Сборники статей Коллекции Цены и условия подписки Begell House Контакты Language English 中文 Русский Português German French Spain