每年出版 6 期
ISSN 打印: 2150-766X
ISSN 在线: 2150-7678
Indexed in
LASER-INDUCED DECOMPOSITION OF [CO(NH3 )5 (CN5 O2 )](CLO4 )2
摘要
Dissociation of water solution of (5-nitrotetrazolato-N2)pentaaminecobalt(III) perchlorate (NCP) under laser irradiation with 355 nm wavelength was investigated by IR and Raman spectroscopy and energy-dispersive spectroscopy analysis. This light energy is in resonance with d-d transitions (1A1g → 1T2g) of Co3+ cations. Condensed products of such dissociation mainly consist of Co3 O4, CoOOH, perchlorate anions, and possibly nitrotetrazolate anions, which differ from the products at conventional thermal decomposition.
-
Kuzmenko A. V., Tverjanovich A. S., Ilyushin M. A., Tveryanovich Yu. S., The effect of the concentration of high-absorbing inclusions on the laser initiation threshold of energetic materials: model and experiment, Journal of Energetic Materials, 37, 4, 2019. Crossref