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International Journal of Energetic Materials and Chemical Propulsion

Erscheint 6 Ausgaben pro Jahr

ISSN Druckformat: 2150-766X

ISSN Online: 2150-7678

The Impact Factor measures the average number of citations received in a particular year by papers published in the journal during the two preceding years. 2017 Journal Citation Reports (Clarivate Analytics, 2018) IF: 0.7 To calculate the five year Impact Factor, citations are counted in 2017 to the previous five years and divided by the source items published in the previous five years. 2017 Journal Citation Reports (Clarivate Analytics, 2018) 5-Year IF: 0.7 The Immediacy Index is the average number of times an article is cited in the year it is published. The journal Immediacy Index indicates how quickly articles in a journal are cited. Immediacy Index: 0.1 The Eigenfactor score, developed by Jevin West and Carl Bergstrom at the University of Washington, is a rating of the total importance of a scientific journal. Journals are rated according to the number of incoming citations, with citations from highly ranked journals weighted to make a larger contribution to the eigenfactor than those from poorly ranked journals. Eigenfactor: 0.00016 The Journal Citation Indicator (JCI) is a single measurement of the field-normalized citation impact of journals in the Web of Science Core Collection across disciplines. The key words here are that the metric is normalized and cross-disciplinary. JCI: 0.18 SJR: 0.313 SNIP: 0.6 CiteScore™:: 1.6 H-Index: 16

Indexed in

HYPERGOLIC REACTION BETWEEN GREEN IONIC LIQUID EMIM SCN AND HYDROGEN PEROXIDE IN LAB-SCALE DROP TEST CHAMBER

Volumen 21, Ausgabe 1, 2022, pp. 87-100
DOI: 10.1615/IntJEnergeticMaterialsChemProp.2021038219
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ABSTRAKT

The hypergolic reaction between the recently developed green propellant combination consisting of an ionic liquid and highly concentrated hydrogen peroxide was investigated for various fuel to oxidizer ratios and heights of fall. The influence of the catalytic copper additive on the ignition delay time (IDT) was analyzed. Flame emission/absorption spectroscopy revealed the chemical constituents. All emission spectra were dominated by the sodium D-lines at a wavelength of λ = 589 nm. Further lines of alkali metals such as lithium and potassium were found. The copper additive showed its characteristic lines according to its amount in the fuel. Emission spectra of the ultraviolet regime showed the characteristic OH* molecular lines around a wavelength of λ = 306 nm with its temperature dependent intensity ratios. The catalytic additive copper (I) thio-cyanate (CuSCN) increases the temperature of the OH* molecule in the flame while it decreases the IDT from 31 ms for pure ionic liquid to 15 ms (5% mass percentage).

REFERENZEN
  1. Balkenhohl, J., Design, Construction and Commissioning of a Reaction Chamber for Hypergolic Fuels as Well as First Optical Measurements of the Flame Emission, Master's, University of Stuttgart, Germany, 2019.

  2. Catoire, L., Chaumeix, N., and Paillard, C., Chemical Kinetic Model for MMH/NTO Gas-Phase Combustion and Hypergolic Ignition, J. Propuls. Power, vol. 20, no. 1, pp. 87-92, 2004.

  3. Catoire, L., Chaumeix, N., Pichon, S., and Paillard, C., Visualizations of Gas-Phase NTO/MMH Reactivity, J. Propuls. Power, vol. 22, no. 1, pp. 120-126,2006.

  4. De Izarra, C., UV OH Spectrum Used as a Molecular Pyrometer, J. Phys. D.: Appl. Phys., vol. 33, no. 14, pp. 1697-1704,2000.

  5. Fiala, T., Sattelmayer, T., Groning, S., Hardi, J., Stiitzer, R., Webster, S., and Oschwald, M., Comparison between Excited Hydroxyl Radical and Blue Radiation from Hydrogen Rocket Combustion, J. Propuls. Power, vol. 33, no. 2, pp. 490-500, 2017.

  6. Gutowski, K.E., Gurkan, B., and Maginn, E.J., Force Field for the Atomistic Simulation of the Properties of Hydrazine, Organic Hydrazine Derivatives, and Energetic Hydrazinium Ionic Liquids, Pure Appl. Chem., vol. 81, pp. 1799-1828, 2009.

  7. Lauck, F., Negri, M., Freudenmann, D., and Schlechtriem, S., Study on Hypergolic Ignition of Ionic Liquid Solutions, Proc. 8th Europ. Conf. Aeronautics Space Sci.s (EUCASS), Madrid, Spain, 2019.

  8. Lauck, F., Negri, M., Freudenmann, D., and Schlechtriem, S., Selection of IL and Characterization of Hypergolicy with Hydrogen Peroxide, Int. J. Energetic Mat. Chem. Propuls., vol. 19, pp. 25-37, 2020.

  9. Lauck, F., Balkenhohl, J., Negri, M., Freudenmann, D., and Schlechtriem, S., GreenBipropellant Development? A Study on the Hypergolicity of Imidazole Thiocyanate Ionic Liquids with Hydrogen Peroxide in an Automated Drop Test Setup, Combust. Flame, vol. 226, pp. 87-97, 2021.

  10. Luque, J. and Crosley, D.R., LIFBASE: Database and Spectral Simulation Program (Version 1.5), SRI International Report MP (99), 1999.

  11. Matsumoto, M., Kano, H., Suzuki, M., Katagiri, T., Umeda, Y., and Fukushima, S., Carcinogenicity and Chronic Toxicity of Hydrazine Monohydrate in Rats and Mice by Two-Year Drinking Water Treatment, Regul. Toxicol. Pharmacol., vol. 76, pp. 63-73,2016.

  12. Navarro, P., Larriba, M., Rojo, E., Garcia, J., and Rodriguez, F., Thermal Properties of Cyano-Based Ionic Liquids, J. Chem. Eng. Data, vol. 58, pp. 2187-2193, 2013.

  13. Nonnenberg, C., Frank, I., and Klapotke, T.M., Ultrafast Cold Reactions in the Bipropellant MMH/NTO: CPMD Simulations, Angew. Chem. Int. Ed., vol. 43, pp. 4585-4589,2004.

  14. Pellerin, S., Cormier, J.M., Richard, F., Musiol, K., and Chapelle, J., A Spectroscopic Method Using UV OH Band Spectrum, J. Phys. D: Appl. Phys, vol. 29, no. 3, pp. 726-739, 1996.

  15. Pringle, J.M., Golding, J., Forsyth, C.M., Deacon, G.B., Forsyth, M., and MacFarlane, D.R., Physical Trends and Structural Features in Organic Salts of the Thiocyanate Anion, J. Mat. Chem.., vol. 12, pp. 3475-3480, 2002.

  16. Stutzer, R. and Oschwald, M., The Hyperfine Structure of the OH Emission Spectrum and its Benefits for Combustion Analysis, Proc. 8th Europ. Conf. Aeronautics Space Sci. (EUCASS), Madrid, Spain, 2019.

  17. Stutzer, R., Bublies, S., Mayer, T., Kraus, S., Clauss, W., and Oschwald, M., Optical Investigation on the Hypergolic MMH/NTO Combustion in Spacecraft Propulsion, Proc. 5th Europ. Conf. Aeronautics Space Sci. (EUCASS), Munich, Germany, 2013.

  18. Stutzer, R., Kraus, S., and Oschwald, M., Investigation of Optical Laser Beam Impairment on Hypergolic Lunar Lander Exhaust Plumes for a Lidar Feasibility Study, CEAS Space J, vol. 12, pp. 481-487,2020.

  19. Vatascin, E. and Dohnal, V., Thermodynamic Properties of Aqueous Solutions of [EMIM] Thiocyanate and [EMIM] Dicyanamide, J. Chem. Thermodynam., vol. 106, pp. 262-275,2017.

  20. Wang, K., Chinnam, A.K., Petrutik, N., Komarala, E.P., Zhang, Q., Yan, Q.-L., Dobrovetsky, R., and Gozin, M., Iodocuprate-Containing Ionic Liquids as Promoters for Green Propulsion, J. Mater. Chem. A, vol. 6, pp. 22819-22829,2018.

  21. Wang, K., Liu, T., Jin, Y., Huang, S., Petrutik, N., Tov, D.S., Yan, Q.-L., Gozin, M., and Zhang, Q., "Tandem-Action" Ferrocenyl Iodocuprates Promoting Low Temperature Hypergolic Ignitions of "Green" EILs-H2O2 Bipropellants, J. Mater. Chem. A, vol. 8, pp. 14661-14670, 2020.

  22. Zaitsau, D.H., Emel'yanenko, V.N., Verevkin, S.P., and Heintz, A., Sulfur-Containing Ionic Liquids. Rotating-Bomb Combustion Calorimetry and First-Principles Calculations for 1-Ethyl-3-Methylimidazolium Thiocyanate, J. Chem. Eng. Data, vol. 55, pp. 5896-5899, 2010.

  23. Zhang, Q., Yin, P., Zhang, J., and Shreeve, J.M., Cyanoborohydride-Based Ionic Liquids as Green Aerospace Bipropellant Fuels, Chem. Eur. J., vol. 20, pp. 6909-6914, 2014.

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