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Journal of Porous Media

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ISSN Imprimer: 1091-028X

ISSN En ligne: 1934-0508

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THE DECLINING AFFINITY OF MICROPOROUS HYDROTALCITE-SILICA MEMBRANE FOR CARBON DIOXIDE

Volume 17, Numéro 2, 2014, pp. 159-167
DOI: 10.1615/JPorMedia.v17.i2.60
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Ahmed Daham Wiheeb
School of Chemical Engineering, Universiti Sains Malaysia 14300 Nibong Tebal, Penang, Malaysia; Chemical Engineering Department, College of Engineering, University of Diyala, Diyala, Iraq
Mohd Azmier Ahmad
School of Chemical Engineering, Universiti Sains Malaysia 14300 Nibong Tebal, Penang, Malaysia
Muhamad Nazri Murat
School of Chemical Engineering, Universiti Sains Malaysia 14300 Nibong Tebal, Penang, Malaysia
J. Kim
Department of Chemical Engineering, Kyung Hee University, Global campus, 1 Seocheon-dong, Giheung-gu, Yongin-si, Gyeonggi-do, 446-701, Republic of Korea
Mohd Roslee Othman
School of Chemical Engineering, Universiti Sains Malaysia, 14300 Nibong Tebal, Penang, Malaysia; Department of Chemical Engineering, Kyung Hee University, Global Campus, 1 Seocheon-dong, Giheung-gu, Yongin-si, Gyeonggi-do 446-701, Republic of Korea

RÉSUMÉ

Single permeation test reveals that excessively high sintering temperature caused unnecessary bloating and collapse of micropores to form meso- and macropore structures. It also caused reduction in carbon dioxide adsorption capacity as a result of diminishing affinitive hydrotalcite phase in the pore structures. The carbon dioxide permeance was higher than that of hydrogen, indicating affinity had greater effect than the diffusivity and molecular sieving. This is also evident from the direction of the carbon dioxide permeance that decreased with increasing sintering temperatures, confirming the dominating surface adsorption mechanism over the ordinary gas diffusion in the membrane within the operating boundaries.

MOTS CLÉS: hydrotalcite, porous membrane, carbon capture, xerogel, permeability
CITÉ PAR

  1. Wiheeb A. D., Ahmad M. A., Murat M. N., Kim J., Othman M. R., Identification of Molecular Transport Mechanisms in Micro-Porous Hydrotalcite–Silica Membrane, Transport in Porous Media, 104, 1, 2014. Crossref

  2. Helwani Z., Wiheeb A. D., Shamsudin I. K., Kim J., Othman M. R., The effects of fractality on hydrogen permeability across meso-porous membrane, Heat and Mass Transfer, 51, 6, 2015. Crossref

  3. Wiheeb A. D., Kim J., Othman M. R., Highly Perm-Selective Micro-Porous Hydrotalcite-Silica Membrane for Improved Carbon Dioxide-Methane Separation, Separation Science and Technology, 50, 11, 2015. Crossref

  4. Wiheeb A. D., Helwani Z., Kim J., Othman M. R., Pressure Swing Adsorption Technologies for Carbon Dioxide Capture, Separation & Purification Reviews, 45, 2, 2016. Crossref

  5. Wiheeb A.D., Mohammed T.E., Abdel-Rahman Z.A., Othman M.R., Flow dynamics of gases inside hydrotalcite-silica micropores, Microporous and Mesoporous Materials, 246, 2017. Crossref

  6. Seman S.Z.A., Idris I., Abdullah A., Shamsudin I.K., Othman M.R., Optimizing purity and recovery of biogas methane enrichment process in a closed landfill, Renewable Energy, 131, 2019. Crossref

  7. Tran Nguyen Tien, Kim Jinsoo, Othman Mohd Roslee, Microporous ZIF-8 and ZIF-67 membranes grown on mesoporous alumina substrate for selective propylene transport, Separation and Purification Technology, 233, 2020. Crossref

  8. Ahmed R.E., Wiheeb A.D., Enhancement of carbon dioxide absorption into aqueous potassium carbonate by adding amino acid salts, Materials Today: Proceedings, 20, 2020. Crossref

  9. Le Van Nhieu, Kim Daekeun, Kim Jinsoo, Othman Mohd Roslee, Freeze Granulation of Nanoporous UiO-66 Nanoparticles for Capture of Volatile Organic Compounds, ACS Applied Nano Materials, 4, 9, 2021. Crossref

  10. Tran Nguyen Tien, Vo The Ky, Kim Jinsoo, Othman Mohd Roslee, Esoteric CO adsorption by CuCl-NiCl2 embedded microporous MIL-101 (Cr), Colloids and Surfaces A: Physicochemical and Engineering Aspects, 615, 2021. Crossref

  11. Go Youngchae, Lee Jeong Hee, Shamsudin Ili Khairunnisa, Kim Jinsoo, Othman Mohd Roslee, Microporous ZIF-7 membranes prepared by in-situ growth method for hydrogen separation, International Journal of Hydrogen Energy, 41, 24, 2016. Crossref

  12. Aceituno Melgar Víctor Manuel, Ahn Howon, Kim Jinsoo, Othman Mohd Roslee, Highly selective micro-porous ZIF-8 membranes prepared by rapid electrospray deposition, Journal of Industrial and Engineering Chemistry, 21, 2015. Crossref

  13. Helwani Z., Aziz N., Kim J., Othman M.R., Improving the yield of Jatropha curcas's FAME through sol–gel derived meso-porous hydrotalcites, Renewable Energy, 86, 2016. Crossref

  14. Liu Yi, Layered Double Hydroxide Membranes for Versatile Separation Applications, in Two‐Dimensional‐Materials‐Based Membranes, 2022. Crossref

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