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Catalysis in Green Chemistry and Engineering

年間 4 号発行

ISSN 印刷: 2572-9896

ISSN オンライン: 2572-990X

H-Index: 2

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V2O5/HMS AS NOVEL CATALYST FOR PRODUCTION OF 1,1'-BI-2-NAPHTHOL BY OXIDATIVE C-C COUPLING OF 2-NAPHTHOL: ACTIVITY, SELECTIVITY AND KINETICS

巻 3, 発行 1, 2020, pp. 13-31
DOI: 10.1615/CatalGreenChemEng.2020034489
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要約

Mesoporous materials such as hexagonal molecular sieve (HMS) can be used as supports for catalysis wherein bulky molecules are involved as reactants or products. The selective oxidative C-C coupling of 2-naphthol to 1,1'-bi-2-naphthol (BINOL) is a challenging reaction, and it was carried out using V2O5/HMS (V-HMS) as the catalyst and molecular oxygen as the oxidizing agent. BINOL is used as a ligand for asymmetric catalysis by transition metals. The redox nature of V2O5, high surface area, larger pore wall thickness, and high thermal stability makes V-HMS the best catalyst for synthesis of bulky BINOL. Different loadings of vanadium on HMS were studied, among which 4% V-HMS was the best. All synthesized and reused catalysts were characterized by TGA-DSC, XRD, H2-TPR, FT-IR, SEM-EDX, TEM, XPS, and BET analysis techniques. 2-Naphthol conversion and BINOL selectivity were 100%. A Mars van Krevelen−type mechanism was proposed, and a kinetic model was built for an oxidative coupling reaction. The apparent activation energy of the reaction system was 15.4 kcal/mol. The catalyst was used repeatedly without any significant loss in activity. The process is green.

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