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High Temperature Material Processes: An International Quarterly of High-Technology Plasma Processes

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ISSN Печать: 1093-3611

ISSN Онлайн: 1940-4360

The Impact Factor measures the average number of citations received in a particular year by papers published in the journal during the two preceding years. 2017 Journal Citation Reports (Clarivate Analytics, 2018) IF: 0.4 The Immediacy Index is the average number of times an article is cited in the year it is published. The journal Immediacy Index indicates how quickly articles in a journal are cited. Immediacy Index: 0.1 The Eigenfactor score, developed by Jevin West and Carl Bergstrom at the University of Washington, is a rating of the total importance of a scientific journal. Journals are rated according to the number of incoming citations, with citations from highly ranked journals weighted to make a larger contribution to the eigenfactor than those from poorly ranked journals. Eigenfactor: 0.00005 The Journal Citation Indicator (JCI) is a single measurement of the field-normalized citation impact of journals in the Web of Science Core Collection across disciplines. The key words here are that the metric is normalized and cross-disciplinary. JCI: 0.07 SJR: 0.198 SNIP: 0.48 CiteScore™:: 1.1 H-Index: 20

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TOLUENE DESTRUCTION BY DBD AT ATMOSPHERIC PRESSURE IN A MULTI-POINT-TO-PLANE REACTOR. REACTION PATHWAYS BY ISOTOPIC LABELLING AND BY-PRODUCT DETERMINATION

Том 9, Выпуск 4, 2005, pp. 531-543
DOI: 10.1615/HighTempMatProc.v9.i4.40
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Depollution process by DBD reactor has been developed in air with toluene, a mono-aromatic molecule that simulates volatile aromatic pollutants (VOCs). The objective of the study is to understand the role of active oxygenate species produced by streamers in oxidation and polymerisation mechanisms of aromatic and polyaromatic compounds. A multi-point-to-plane plasma reactor is used. Discharge is produced by an AC 45 kHz HV generator and is electrically characterized by a 0.5 GHz numerical oscilloscope. An O2 (10%vol), H2O (1,8%vol), 700 or 300 ppmv toluene in N2 mixture is treated at atmospheric pressure and 100°C. A qualitative and quantitative chemical analysis of gas effluent and suspended particles is realized by Gas Chromatography coupled with a Mass Spectrometer in order to understand the pulsed discharge chemical reactivity. Alkanes, alkenes, oxidized molecules such as acetone and benzaldehyde, R-NOx (C2H5NO2, CH3ONO2) and heavy molecules such as octadecane-2-methyl, methylolpinene or anthracene have been identified. Labeled molecules, 18O2 and (C6H6)-CD3, are added in order to identify chemical pathways, especially toluene destruction. The active species coming from air oxygen lead to oxidation reactions with carbon chain cleavage whereas oxidants coming from H2O lead rather to addition reactions.

ЦИТИРОВАНО В
  1. Blin-Simiand N., Jorand F., Magne L., Pasquiers S., Postel C., Vacher J.-R., Plasma Reactivity and Plasma-Surface Interactions During Treatment of Toluene by a Dielectric Barrier Discharge, Plasma Chemistry and Plasma Processing, 28, 4, 2008. Crossref

  2. Kim Hyun-Ha, Ogata Atsushi, Schiorlin Milko, Marotta Ester, Paradisi Christina, Oxygen Isotope (18O2) Evidence on the Role of Oxygen in the Plasma-Driven Catalysis of VOC Oxidation, Catalysis Letters, 141, 2, 2011. Crossref

  3. Martin Laure, Ognier Stéphanie, Gasthauer Estelle, Cavadias Simeon, Dresvin Sergei, Amouroux Jacques, Destruction of Highly Diluted Volatile Organic Components (VOCs) in Air by Dielectric Barrier Discharge and Mineral Bed Adsorption, Energy & Fuels, 22, 1, 2008. Crossref

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