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High Temperature Material Processes: An International Quarterly of High-Technology Plasma Processes

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ISSN Druckformat: 1093-3611

ISSN Online: 1940-4360

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THE FORMATION OF SURFACE Ti-Al-V-Cu ALLOY BY COMBINED ION-PLASMA TREATMENT

Volumen 26, Ausgabe 1, 2022, pp. 33-39
DOI: 10.1615/HighTempMatProc.2022042089
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ABSTRAKT

In this work, surface Ti-Cu-Al-V alloy was synthesized by compression plasma flows impact on Ti-6Al-4V titanium alloy preliminarily coated by copper. The treatment of Cu/Ti-6Al-4V samples was carried out by three pulses of compression plasma flows generated in the nitrogen atmosphere (energy density absorbed by the surface was varied in the range of 26-43 J/cm2 per pulse). The phase and elemental composition, structure, microhardness and friction coefficient of the formed surface alloy were investigated. It has been established that plasma treatment resulted in the formation of α-Ti solid solution containing alloying elements in the surface layer and δ-TiN on the surface. An increase of the energy absorbed by the surface during plasma impact led to a decrease of Cu concentration (2.7-0.5 wt %) in the analyzed layer. The surface alloy was characterized by a uniform distribution of Ti, Al, and Vatoms in contrast to the distribution of these elements on the surface of the untreated Ti-6Al-4V alloy. The microhardness increase up to 4.7 GPa (1.3 times higher in comparison with initial Ti-6Al-4 Valloy) was found after compression plasma flows treatment at 43 J/cm2. Tribological tests showed that the minimal friction coefficient (0.13) was observed after treatment at the absorbed energy density of 26 J/cm2.

Figures

  • Dependence of the mass removed from surface unit area of Cu/Ti-6Al-4V system samples on the
energy density absorbed by the surface
  • Distribution of elements Ti, Al, V, and Cu along arbitrary lines on the surface of the initial sample
(а) and the sample of the Cu/Ti-6Al-4V system after CPF treatment (Q = 26 J/cm2) (b)
  • Diffraction patterns of the Cu/Ti-6Al-4V system samples before and after CPF treatment
  • SEM images of samples’ surface after CPF treatment at Q = 43 J/cm2
  • Microhardness of Ti-6Al-4V alloy sample and Cu/Ti-6Al-4V system samples after CPF treatment
at Q = 26 J/cm2 and Q = 43 J/cm2
  • Friction coeffcient dependence on the indenter sliding distance of Ti-6Al-4V sample and Cu/
Ti-6Al-4V system samples after CPF treatment at Q = 26 J/cm2 and Q = 43 J/cm2
REFERENZEN
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  2. Cherenda, N.N., Basalai, A.V., Uglov, V.V., Laskovnev, A.P., Astashynski, V.M., and Kuzmitski, A.M., Phase Composition and Mechanical Properties of Cu-Ti Alloys Synthesized in the Surface Layer of Copper by Plasma Impact on the Ti/Cu System, Vacuum, vol. 167, pp. 452-458, 2019.

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